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典型文献
Ether-/Ester-/Fluorine-Rich Binding Emulsion Formula for Lithium-Ion Batteries
文献摘要:
Practical application of a Si anode in a high-energy-density battery cannot be achieved due to the huge volume expansion of these anodes.Researchers have focused on binders of the anode to restrict volume expansion in order to address this issue,as the hydrogen bonds and mechanical properties of binders can be used to enhance adhesion and accommodate the volume changes of a Si anode.Herein,we compre-hensively consider binders'hydrogen bonds,mechanical properties,stability,and compatibility with the electrolyte solution,and design an ether-/ester-/fluorine-rich composite polymer,named P(TFEMA-co-IBVE).The proposed binder formula possesses outstanding stability,adhesion,and mechanical strength;moreover,it can accommodate the dramatic volume changes of a Si electrode and exhibits excellent elec-trochemical performance,achieving a high areal capacity of about 5.4 mA·h·cm-2.This novel polymer design may be applied to other electrode materials in the next generation of lithium-ion batteries.
文献关键词:
作者姓名:
Xianqing Zeng;Donglin Han;Zeheng Li;Hongxun Wang;Gu Wu;Yong Deng;Kai Liu;Li Xie;Chengdu Liang;Min Ling;Yuchuan Huang
作者机构:
China Tobacco Sichuan Industrial Co.,Ltd.,Chengdu 610066,China;Key Laboratory of Biomass Chemical Engineering of the Ministry of Education,College of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310027,China;School of Metallurgy and Environment,Central South University,Changsha 410083,China;Sichuan Sanlian New Material Co.,Ltd.,Chengdu 610041,China
文献出处:
引用格式:
[1]Xianqing Zeng;Donglin Han;Zeheng Li;Hongxun Wang;Gu Wu;Yong Deng;Kai Liu;Li Xie;Chengdu Liang;Min Ling;Yuchuan Huang-.Ether-/Ester-/Fluorine-Rich Binding Emulsion Formula for Lithium-Ion Batteries)[J].工程(英文),2022(12):199-206
A类:
TFEMA,IBVE
B类:
Ether,Ester,Fluorine,Rich,Binding,Emulsion,Formula,Lithium,Ion,Batteries,Practical,application,Si,high,energy,density,battery,cannot,be,achieved,due,huge,volume,expansion,these,anodes,Researchers,have,focused,binders,restrict,order,address,this,issue,as,hydrogen,bonds,mechanical,properties,enhance,adhesion,accommodate,changes,Herein,we,compre,hensively,consider,stability,compatibility,electrolyte,solution,design,ether,ester,fluorine,rich,composite,polymer,named,proposed,formula,possesses,outstanding,strength,moreover,dramatic,electrode,exhibits,excellent,trochemical,performance,achieving,areal,capacity,about,mA,This,novel,may,applied,other,materials,next,generation,lithium,batteries
AB值:
0.642609
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