典型文献
Azobenzene-Based Solar Thermal Fuels:A Review
文献摘要：
The energy storage mechanism of azobenzene is based on the transformation of molecular cis and trans isomeri-zation,while NBD/QC,DHA/VHF,and fulvalene dimetal complexes realize the energy storage function by changing the molecular structure.Acting as"molecular batteries,"they can exhibit excellent charging and discharging behavior by con-verting between trans and cis isomers or changing molecular structure upon absorption of ultraviolet light.Key properties determining the performance of STFs are stored energy,energy density,half-life,and solar energy conversion efficiency.This review is aiming to provide a comprehensive and authoritative overview on the recent advancements of azobenzene molecular photoswitch system in STFs fields,including derivatives and carbon nano-templates,which is emphasized for its attractive performance.Although the energy storage performance of Azo-STFs has already reached the level of commercial lithium batteries,the cycling capability and controllable release of energy still need to be further explored.For this,some potential solutions to the cycle per-formance are proposed,and the methods of azobenzene controllable energy release are summarized.Moreover,energy stored by STFs can be released in the form of mechanical energy,which in turn can also promote the release of thermal energy from STFs,implying that there could be a relationship between mechanical and thermal energy in Azo-STFs,providing a potential direction for further research on Azo-STFs.
文献关键词：
中图分类号：
作者姓名：
Bo Zhang;Yiyu Feng;Wei Feng
作者机构：
School of Materials Science and Engineering,Tianjin University,Tianjin 300350,People's Republic of China;Tianjin Key Laboratory of Composite and Functional Materials,Tianjin 300350,People's Republic of China;Key Laboratory of Materials Processing and Mold,Ministry of Education,Zhengzhou University,Zhengzhou 450002,People's Republic of China
文献出处：
引用格式：
[1]Bo Zhang;Yiyu Feng;Wei Feng-.Azobenzene-Based Solar Thermal Fuels:A Review)[J].纳微快报（英文）,2022(08):232-268
A类：
Azobenzene,isomeri,fulvalene,dimetal,verting,STFs,photoswitch
B类：
Based,Solar,Thermal,Fuels,Review,energy,storage,mechanism,azobenzene,transformation,molecular,cis,zation,while,NBD,QC,DHA,VHF,complexes,realize,function,by,changing,structure,Acting,batteries,they,can,exhibit,excellent,discharging,behavior,between,isomers,upon,absorption,ultraviolet,light,Key,properties,determining,performance,are,stored,density,half,life,solar,conversion,efficiency,This,review,aiming,provide,comprehensive,authoritative,overview,recent,advancements,system,fields,including,derivatives,carbon,nano,templates,which,emphasized,its,attractive,Although,already,reached,level,commercial,lithium,cycling,capability,controllable,still,need,further,explored,For,this,potential,solutions,cycle,proposed,methods,summarized,Moreover,released,mechanical,turn,also,promote,thermal,from,implying,that,there,could,relationship,providing,direction,research
AB值：
0.504202
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