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Advances of PtRu-Based Electrocatalysts for Methanol Oxidation
文献摘要:
Platinum-Ruthenium(PtRu)-based materials are considered the"holy grail"of electrocatalysts for methanol oxidation reaction(MOR)in the fuel cells technique.However,to the best of our knowledge,the exhaustive review report on the advance of PtRu materi-als for methanol oxidation is rarely summarized for the recent novel achievements.Herein,we summarize and discuss the latest progress of PtRu-based catalysts in MOR.The reac-tion mechanism of MOR is firstly introduced,and the promotion mechanism is revealed by the relevant activity descriptor,the in-situ spectroscopic analysis and the theoretical calcu-lation.Subsequently,some advanced regulation strategies of PtRu-based catalysts are concluded,including support engineering,morphology design and surface interface regula-tion.Finally,the challenges and opportunities to improve the MOR performance of PtRu-based electrocatalysts are prospected to further promote the widespread application of PtRu-based catalysts in electrocatalytic systems.It is concluded that many efforts are still required to decipher the atomic scale structure-activity relationship and the structural changes of atoms and electrons in the reaction process by advanced strategies and char-acterization methods.Hopefully,this review can be helpful for novel PtRu-based catalyst development and understanding their corre-lation to the structure and performance of energy-relevant electrocatalysis.
文献关键词:
作者姓名:
Wei Qiao;Xingyu Huang;Ligang Feng
作者机构:
School of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou 225002,China
文献出处:
引用格式:
[1]Wei Qiao;Xingyu Huang;Ligang Feng-.Advances of PtRu-Based Electrocatalysts for Methanol Oxidation)[J].结构化学,2022(07):16-34
A类:
B类:
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AB值:
0.566184
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