典型文献
Stable Zinc Anodes Enabled by Zincophilic Cu Nanowire Networks
文献摘要：
Zn-based electrochemical energy storage (EES) sys-tems have received tremendous attention in recent years,but their zinc anodes are seriously plagued by the issues of zinc dendrite and side reactions (e.g.,corrosion and hydrogen evolution).Herein,we report a novel strategy of employing zincophilic Cu nanowire networks to stabilize zinc anodes from multiple aspects.According to experimen-tal results,COMSOL simulation and density functional theory cal-culations,the Cu nanowire networks covering on zinc anode surface not only homogenize the surface electric field and Zn2+ concentration field,but also inhibit side reactions through their hydrophobic feature.Meanwhile,facets and edge sites of the Cu nanowires,especially the latter ones,are revealed to be highly zincophilic to induce uniform zinc nucleation/deposition.Consequently,the Cu nanowire networks-protected zinc anodes exhibit an ultralong cycle life of over 2800 h and also can continuously operate for hundreds of hours even at very large charge/discharge currents and areal capacities (e.g.,10 mA cm-2 and 5 mAh cm-2),remarkably superior to bare zinc anodes and most of currently reported zinc anodes,thereby enabling Zn-based EES devices to possess high capacity,16,000-cycle lifespan and rapid charge/discharge ability.This work provides new thoughts to realize long-life and high-rate zinc anodes.
文献关键词：
中图分类号：
作者姓名：
Shiyin Xie;Yang Li;Xu Li;Yujun Zhou;Ziqi Dang;Jianhua Rong;Liubing Dong
作者机构：
College of Chemistry and Materials Science,Jinan University,Guangzhou 511443,People's Republic of China
文献出处：
引用格式：
[1]Shiyin Xie;Yang Li;Xu Li;Yujun Zhou;Ziqi Dang;Jianhua Rong;Liubing Dong-.Stable Zinc Anodes Enabled by Zincophilic Cu Nanowire Networks)[J].纳微快报（英文）,2022(02):311-323
A类：
Zincophilic,zincophilic
B类：
Stable,Anodes,Enabled,Nanowire,Networks,electrochemical,energy,storage,EES,sys,tems,have,received,tremendous,attention,recent,years,but,their,anodes,seriously,plagued,issues,dendrite,side,reactions,corrosion,hydrogen,evolution,Herein,we,novel,strategy,employing,networks,stabilize,from,multiple,aspects,According,experimen,tal,results,COMSOL,simulation,density,functional,theory,culations,covering,surface,not,only,homogenize,electric,field,Zn2+,concentration,also,inhibit,through,hydrophobic,feature,Meanwhile,facets,edge,sites,nanowires,especially,latter,ones,revealed,be,highly,induce,uniform,nucleation,deposition,Consequently,protected,exhibit,ultralong,cycle,can,continuously,operate,hundreds,hours,even,very,large,discharge,currents,areal,capacities,mAh,remarkably,superior,bare,most,currently,reported,thereby,enabling,devices,possess,capacity,lifespan,rapid,ability,This,provides,new,thoughts,realize
AB值：
0.614486
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
