Enormous demands on the separation of oil/water(O/W)emulsions in various industries,such as petro-chemical,food and pharmaceutical industries,are looking for high performance and energy-efficient sep-aration methods.Ceramic membranes have been used to deal with O/W emulsions,for its outstanding characteristics of easy-operation,high-flux,and long-term stability.However,membrane fouling is still a challenge in the industrial application of ceramic membranes.Herein,antifouling ceramic membranes were fabricated by grafting zwitterions on the membrane surface via an environment-friendly two-step grafting method,which improves the antifouling property and permeability.Successful grafting of such zwitterion on the ceramic surface was assessed by the combination of FTIR and XPS characterization.More importantly,the hydration can be formed by electrostatic interactions layer on the modified mem-brane,which was confirmed by TGA characterization.The antifouling performance of prepared zwitteri-onic ceramic membranes in the separation of O/W emulsions was systematically tested.The results suggested that zwitterion can significantly improve the flux of ceramic ultrafiltration membrane,and can also improve antifouling property dramatically by reducing the irreversible fouling in the separation of O/W emulsions.Therefore,zwitterionic ceramic membranes hold promising potentials as an antifoul-ing,highly efficient and green method in the practical purification of the O/W emulsions.

Tianyu Zhang;Qian Wang;Wei Luan;Xue Li;Xianfu Chen;Dong Ding;Zhichao Shen;Minghui Qiu;Zhaoliang Cui;Yiqun Fan

State Key Laboratory of Materials-Oriented Chemical Engineering,National Engineering Research Center for Special Separation Membranes,College of Chemical Engineering,Nanjing Tech University,Nanjing 211816,China;Zhangjiagang Institute of Nanjing Tech University,Suzhou 215699,China

中国化学工程学报（英文版）

[1]Tianyu Zhang;Qian Wang;Wei Luan;Xue Li;Xianfu Chen;Dong Ding;Zhichao Shen;Minghui Qiu;Zhaoliang Cui;Yiqun Fan-.Zwitterionic monolayer grafted ceramic membrane with an antifouling performance for the efficient oil-water separation)[J].中国化学工程学报（英文版）,2022(02):227-235

zwitterions,zwitteri,antifoul

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