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典型文献
Minimising non-selective defects in ultrathin reduced graphene oxide membranes with graphene quantum dots for enhanced water and NaCl separation
文献摘要:
Reduced graphene oxide (rGO) membranes have been intensively evaluated for desalination and ionic sieving applications,benefiting from their stable and well-confined interlayer channels.However,rGO membranes generally suffer from low permeability due to the high transport resistance resulting from the narrowed two-dimensional (2D) channels.Although high permeability can be realized by reducing membrane thickness,membrane selectivity normally declines because of the formation of non-selective defects,in particular pinholes.In this study,we demonstrate that the non-selective defects in ultrathin rGO membranes can be effectively minimised by a facile posttreatment via surface-deposition of graphene quantum dots (GQDs).The resultant GQDs/rGO membranes obtained a good trade-off between water permeance (14 L·m-2·h-1·MPa-1) and NaCl rejection (91%).This work provides new insights into the design of high quality ultrathin 2D laminar membranes for desalination,molecular/ionic sieving and other separation applications.
文献关键词:
作者姓名:
Shi Yuan;Yang Li;Ruosang Qiu;Yun Xia;Cordelia Selomulya;Xiwang Zhang
作者机构:
Department of Chemical Engineering,Monash University,Clayton,Victoria 3800,Australia;School of Chemical Engineering,University of New South Wales,New South Wales 2052,Australia
引用格式:
[1]Shi Yuan;Yang Li;Ruosang Qiu;Yun Xia;Cordelia Selomulya;Xiwang Zhang-.Minimising non-selective defects in ultrathin reduced graphene oxide membranes with graphene quantum dots for enhanced water and NaCl separation)[J].中国化学工程学报(英文版),2022(01):278-285
A类:
Minimising
B类:
selective,defects,ultrathin,reduced,graphene,oxide,membranes,quantum,dots,enhanced,water,NaCl,separation,Reduced,rGO,have,been,intensively,evaluated,desalination,ionic,sieving,applications,benefiting,from,their,stable,well,confined,interlayer,channels,However,generally,suffer,low,permeability,due,high,transport,resistance,resulting,narrowed,two,dimensional,2D,Although,can,realized,by,reducing,thickness,selectivity,normally,declines,because,formation,particular,pinholes,In,this,study,demonstrate,that,effectively,minimised,facile,posttreatment,via,surface,deposition,GQDs,resultant,obtained,good,trade,off,between,permeance,rejection,This,work,provides,new,insights,into,design,quality,laminar,molecular,other
AB值:
0.615444
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