典型文献
Asymmetric synthesis of binaphthyls through photocatalytic cross-coupling and organocatalytic kinetic resolution
文献摘要：
By capitalizing on the capability of photoredox catalysis to generate reactive radical intermediate under mild conditions,we established a photocatalytic cross-coupling protocol that could deliver both derivatives from 1-bromo-2-naphthols in com-bination with 2-naphthols or 2-naphthylamines.This distinct activation mode could overcome structural or electronic limitation associated with conventional coupling pathways.Additionally,a novel kinetic resolution protocol of unprotected BINOLs has been established with azodicarboxylates via chiral phosphoric acid(CPA)catalysis.Selectivity factor of up to 175 could be achieved and delivered to both enantiomers in atropisomerically enriched form after a simple work-up.
文献关键词：
中图分类号：
作者姓名：
Heng-Hui Li;Jia-Yan Zhang;Shaoyu Li;Yong-Bin Wang;Jun Kee Cheng;Shao-Hua Xiang;Bin Tan
作者机构：
School of Chemistry and Chemical Engineering,Harbin Institute of Technology,Harbin 150001,China;Shenzhen Grubbs Institute,Department of Chemistry and Guangdong Provincial Key Laboratory of Catalysis,Southern University of Science and Technology,Shenzhen 518055,China;Academy for Advanced Interdisciplinary Studies,Southern University of Science and Technology,Shenzhen 518055,China
文献出处：
引用格式：
[1]Heng-Hui Li;Jia-Yan Zhang;Shaoyu Li;Yong-Bin Wang;Jun Kee Cheng;Shao-Hua Xiang;Bin Tan-.Asymmetric synthesis of binaphthyls through photocatalytic cross-coupling and organocatalytic kinetic resolution)[J].中国科学:化学（英文版）,2022(06):1142-1148
A类：
binaphthyls,naphthols,naphthylamines,BINOLs,azodicarboxylates,atropisomerically
B类：
Asymmetric,synthesis,through,photocatalytic,cross,coupling,organocatalytic,kinetic,resolution,By,capitalizing,capability,photoredox,catalysis,generate,reactive,radical,intermediate,under,mild,conditions,we,established,protocol,that,could,both,derivatives,from,bromo,bination,This,distinct,activation,mode,overcome,structural,electronic,limitation,associated,conventional,pathways,Additionally,novel,unprotected,has,been,via,chiral,phosphoric,acid,CPA,Selectivity,achieved,delivered,enantiomers,enriched,form,after,simple,work
AB值：
0.617053
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
