典型文献
High-performance nonfused ring electron acceptor with a steric hindrance induced planar molecular backbone
文献摘要：
Three nonfused ring electron acceptors(NFREAs)TTC6,TT-C8T and TT-TC8 were purposefully designed and synthesized.The molecular geometry can be adjusted by the steric hindrance of lateral substituents.According to the DFT calculations,from TTC6 to TT-C8T and TT-TC8,planarity of the molecular backbone is gradually improved,accompanying with the enhancing of intramolecular charge transfer effect.As for TT-TC8,the two phenyl substituents are almost perpendicular to the molecular backbone,which endues the acceptor with good solubility and suppresses it to form over-aggregation.Multidirectional regular molecular orientation and closer molecular stacking are formed in TT-TC8 film.As a result,TT-TC8 based devices afford the highest PCE of 13.13％,which is much higher than that of TTC6(4.41％)and TT-C8T(10.42％)and among the highest PCE values based on NFREAs.
文献关键词：
中图分类号：
作者姓名：
Hao Lu;Xiaodong Wang;Hang Wang;Andong Zhang;Xinming Zheng;Na Yu;Zheng Tang;Xinjun Xu;Yahui Liu;Ya-Nan Chen;Zhishan Bo
作者机构：
College of Textiles&Clothing,State Key Laboratory of Bio-fibers and Eco-textiles,Qingdao University,Qingdao 266071,China;Beijing Key Laboratory of Energy Conversion and Storage Materials,College of Chemistry,Beijing Normal University,Beijing 100875,China;Center for Advanced Low-Dimension Materials,State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering,Donghua University,Shanghai 201620,China
文献出处：
引用格式：
[1]Hao Lu;Xiaodong Wang;Hang Wang;Andong Zhang;Xinming Zheng;Na Yu;Zheng Tang;Xinjun Xu;Yahui Liu;Ya-Nan Chen;Zhishan Bo-.High-performance nonfused ring electron acceptor with a steric hindrance induced planar molecular backbone)[J].中国科学:化学（英文版）,2022(03):594-601
A类：
nonfused,NFREAs,TTC6,C8T,endues,Multidirectional
B类：
High,performance,ring,electron,steric,hindrance,induced,backbone,Three,acceptors,TC8,were,purposefully,designed,synthesized,geometry,can,be,adjusted,by,lateral,substituents,According,DFT,calculations,from,planarity,is,gradually,improved,accompanying,enhancing,intramolecular,charge,transfer,effect,two,phenyl,are,almost,perpendicular,which,good,solubility,suppresses,over,aggregation,regular,orientation,closer,stacking,formed,film,result,devices,afford,highest,PCE,much,higher,than,that,among,values
AB值：
0.458897
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
