典型文献
Simple hybrid dithiafulvenes-triphenylamine systems as dopant-free hole-transporting materials for efficient perovskite solar cells
文献摘要：
Two extended hybrid conjugated systems based on a triphenylamine(TPA)core with two and three peripheral 1,4-dithiafulvenes(DTF)units coded WH-2 and WH-3 as hole-transporting materials(HTMs)applied in perovskite solar cells(PSCs)are synthesized by facile one-step reaction in good yield over 75％.DTF unit as electron donor can enhance the electron donating ability and the fusion of benzenic ring of TPA with DTF unit may lead to reinforced intermolecular interactions in the solid state.In addition,WH-2 and WH-3 exhibit a pyramid shape containing partial planarity and quasi three-dimensionality features,which is also conducive to enhancing the π-π stacking of molecules in the solid state.The above-mentioned structural characteristics make the two HTMs have good hole mobilities.As a result,WH-2 and WH-3 obtained the high intrinsic hole mobilities of 4.69×10-4 and 2.18×10-3 cm2 V-1 s-1 respectively.Finally,the power conversion efficiencies(PCEs)of PSCs with WH-2 and WH-3 as cost-effective dopant-free HTMs are 15.39％and 19.22％respectively and the PCE of PSC with WH-3 is on a par with that of PSC with Li-TFSI/t-BP doped Spiro-OMeTAD(19.67％).
文献关键词：
中图分类号：
作者姓名：
Zhongquan Wan;Yunpeng Zhang;Jinyu Yang;Jianxing Xia;Fangyan Lin;Xiaojun Yao;Junsheng Luo;Chunyang Jia
作者机构：
State Key Laboratory of Electronic Thin Films and Integrated Devices,School of Electronic Science and Engineering,University of Electronic Science and Technology of China,Chengdu 610054,Sichuan,China;State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,Gansu,China
文献出处：
引用格式：
[1]Zhongquan Wan;Yunpeng Zhang;Jinyu Yang;Jianxing Xia;Fangyan Lin;Xiaojun Yao;Junsheng Luo;Chunyang Jia-.Simple hybrid dithiafulvenes-triphenylamine systems as dopant-free hole-transporting materials for efficient perovskite solar cells)[J].能源化学,2022(05):293-299
A类：
dithiafulvenes,benzenic
B类：
Simple,hybrid,triphenylamine,systems,dopant,free,hole,transporting,materials,efficient,perovskite,solar,cells,Two,extended,conjugated,TPA,core,two,three,peripheral,DTF,units,coded,WH,HTMs,applied,PSCs,are,synthesized,by,facile,step,reaction,good,yield,over,electron,donor,can,enhance,donating,ability,fusion,ring,may,lead,reinforced,intermolecular,interactions,solid,state,In,addition,exhibit,pyramid,shape,containing,partial,planarity,quasi,dimensionality,features,which,also,conducive,enhancing,stacking,molecules,above,mentioned,structural,characteristics,make,have,mobilities,result,obtained,high,intrinsic,respectively,Finally,power,conversion,efficiencies,PCEs,cost,effective,that,Li,TFSI,doped,Spiro,OMeTAD
AB值：
0.547191
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