典型文献
Hexnut[12]arene and its derivatives:Synthesis,host-guest properties,and application as nonporous adaptive crystals
文献摘要：
Hexnut[12]arene(HN[12])and its derivatives,a new class of sixfold macrocyclic arenes,were designed and synthesized in reasonable yield by a one-pot reaction at room temperature using dimethoxymethane as a methylene source.HN[12],which bears a large,symmetric,and rigid cavity,was easily functionalized at both the methylene bridges and the hydroquinone units.A water-soluble fluorescent HN[12]was synthesized and used as a host to encapsulate benzyl viologen dichloride in water with a high binding affinity of(3.4±0.2)x 106 M-1.The nonporous adaptive crystal(NAC)of HN[12]was found to capture not only inorganic molecules(iodine)but also trace amounts of large organic molecules(basic fuchsine)from water,which greatly expands the scope of NACs for adsorption.
文献关键词：
中图分类号：
作者姓名：
Jian Cheng;Bingbing Gao;Hao Tang;Zhihong Sun;Linxian Xu;Lingyun Wang;Derong Cao
作者机构：
State Key Laboratory of Luminescent Materials and Devices,School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510641,China
文献出处：
引用格式：
[1]Jian Cheng;Bingbing Gao;Hao Tang;Zhihong Sun;Linxian Xu;Lingyun Wang;Derong Cao-.Hexnut[12]arene and its derivatives:Synthesis,host-guest properties,and application as nonporous adaptive crystals)[J].中国科学:化学（英文版）,2022(03):539-545
A类：
Hexnut,nonporous,dimethoxymethane,fuchsine
B类：
derivatives,Synthesis,host,guest,properties,application,adaptive,crystals,HN,new,class,sixfold,macrocyclic,arenes,were,designed,synthesized,reasonable,yield,by,pot,reaction,room,temperature,using,methylene,source,which,bears,large,symmetric,rigid,cavity,was,easily,functionalized,both,bridges,hydroquinone,units,water,soluble,fluorescent,used,encapsulate,benzyl,viologen,dichloride,high,binding,affinity,found,capture,not,only,inorganic,molecules,iodine,but,also,trace,amounts,basic,from,greatly,expands,scope,NACs,adsorption
AB值：
0.609303
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机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
