典型文献
Efficient hydrogenation of furfural to furfuryl alcohol by magnetically recoverable RuCo bimetallic catalyst
文献摘要：
A magnetically recoverable RuCo bimetallic catalyst was reported for the catalytic hydrogenation of furfural to furfuryl alcohol under ambient H2 pressure.The magnetic catalyst was prepared by H2 treatment of the RuCo composite precursor from a facile one-pot hydrolysis of Co and Ru salts by NaBH4 solution.This catalyst can totally convert furfural to 98-100％furfuryl alcohol at 120℃under 1 bar H2 in iso-propanol or water using only molecular H2 as hydrogen source.Moreover,the catalyst showed excellent stability during recycling test and can be easily and completely recovered by magnet from reaction solution.The influence of Ru/Co ratio and H2-treatment temperature was studied,which were shown to be important for the structural evolution and the metal interaction in RuCo active sites,based on the comprehensive characterizations including XRD,TGA,TEM,XPS,H2-TPR,CO adsorbed DRIFT-IR.It was demonstrated that the cooperative Ru0-Co0 bimetallic active sites in strong interaction can significantly promote activity and selectivity of the catalyst due to an enhanced adsorption and activation of furfural and H2,and simultaneously created a strong magnetism in the RuCo catalyst for simple physical separation.
文献关键词：
中图分类号：
作者姓名：
Yongxing Wang;Tianyu Gao;Yaowei Lu;Yinghao Wang;Qiue Cao;Wenhao Fang
作者机构：
School of Chemical Science and Technology,Key Laboratory of Medicinal Chemistry for Natural Resource-Ministry of Education,Yunnan University,Kunming,650091,China;National Demonstration Center for Experimental Chemistry and Chemical Engineering Education,Yunnan University,Kunming,650091,China
文献出处：
引用格式：
[1]Yongxing Wang;Tianyu Gao;Yaowei Lu;Yinghao Wang;Qiue Cao;Wenhao Fang-.Efficient hydrogenation of furfural to furfuryl alcohol by magnetically recoverable RuCo bimetallic catalyst)[J].绿色能源与环境（英文）,2022(02):275-287
A类：
RuCo,Ru0
B类：
Efficient,hydrogenation,furfural,furfuryl,alcohol,by,magnetically,recoverable,bimetallic,catalyst,was,reported,catalytic,under,ambient,H2,pressure,prepared,treatment,composite,precursor,from,facile,one,pot,hydrolysis,salts,NaBH4,solution,This,totally,convert,bar,iso,propanol,water,using,only,molecular,source,Moreover,showed,excellent,stability,during,recycling,test,easily,completely,recovered,reaction,influence,temperature,studied,which,were,shown,important,structural,evolution,interaction,active,sites,comprehensive,characterizations,including,TGA,TEM,XPS,TPR,adsorbed,DRIFT,It,demonstrated,that,cooperative,Co0,strong,significantly,promote,activity,selectivity,due,enhanced,adsorption,activation,simultaneously,created,magnetism,simple,physical,separation
AB值：
0.516077
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
