典型文献
Hydrothermal synthesized delafossite CuGaO2 as an electrocatalyst for water oxidation
文献摘要:
Hydrogen production from water splitting provides an effective method to alleviate the ever-growing global energy crisis.In this work,delafossite CuGaO2(CGO)crystal was synthesized through hydrothermal routes with Cu(NO3)2·3H2O and Ga(NO3)3·xH2O used as reactants.The addition of cetyltrimethylammonium bromide(CTAB)was found to play an important role in modifying the morphology of CuGaO2(CGO-CTAB).With the addition of CTAB,the morphology of CGO-CTAB samples changed from irregular flake to typical hexagonal sheet microstructure,with an average size of 1-2 pm and a thick-ness of around 100 nm.Furthermore,the electrocatalytic activity of CGO-CTAB crystals for oxygen evolution reaction(OER)was also studied and compared with that of CGO crystals.CGO-CTAB samples exhibited better activity than CGO.An overpotential of 391.5 mV was shown to be able to generate a current density of 10 mA/cm2.The as-prepared samples also demonstrate good stability for water oxidation and relatively fast OER kinetics with a Tafel slope of 56.4 mV/dec.This work highlights the significant role of modification of CTAB surfactants in preparing CGO related crystals,and the introduc-tion of CTAB was found to help to improve their electrocatalytic activity for OER.
文献关键词:
中图分类号:
作者姓名:
Han Gao;Miao Yang;Xing Liu;Xianglong Dai;Xiao-Qing Bao;Dehua Xiong
作者机构:
State Key Laboratory of Silicate Materials for Architectures,Wuhan University of Technology,Wuhan 430070,China;Wuhan National Laboratory for Optoelectronics,Huazhong University of Science and Technology,Wuhan 430074,China;State Key Laboratory of Optical Technologies on Nanofabrication and Microengineering,Institute of Optics and Electronics,Chinese Academy of Sciences,Chengdu 610209,China
文献出处:
引用格式:
[1]Han Gao;Miao Yang;Xing Liu;Xianglong Dai;Xiao-Qing Bao;Dehua Xiong-.Hydrothermal synthesized delafossite CuGaO2 as an electrocatalyst for water oxidation)[J].光电子前沿(英文版),2022(01):80-91
A类:
delafossite,CuGaO2
B类:
Hydrothermal,synthesized,electrocatalyst,water,oxidation,Hydrogen,production,from,splitting,provides,effective,method,alleviate,ever,growing,global,energy,crisis,In,this,work,CGO,was,through,hydrothermal,routes,NO3,3H2O,xH2O,used,reactants,addition,cetyltrimethylammonium,bromide,CTAB,found,play,important,role,modifying,morphology,With,samples,changed,irregular,flake,typical,hexagonal,sheet,microstructure,average,pm,thick,ness,around,Furthermore,electrocatalytic,activity,crystals,oxygen,evolution,reaction,OER,also,studied,compared,that,exhibited,better,than,An,overpotential,mV,shown,able,generate,current,density,mA,prepared,demonstrate,good,stability,relatively,fast,kinetics,Tafel,slope,dec,This,highlights,significant,modification,surfactants,preparing,related,introduc,help,improve,their
AB值:
0.547003
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