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典型文献
Heat treatment-induced Co3+enrichment in CoFePBA to enhance OER electrocatalytic performance
文献摘要:
Increasing active metal sites is a valid approach to improve the catalytic activity of the catalyst.Co3+is the main active metal site of Co-based catalysts.In this research work,through the partial transforma-tion of CoFePBA(CFP)via low-temperature heat treatment,the effective control of the Co3+/Co2+ratio has been achieved.The partial transformation strategy of low-temperature heat treatment can not only maintain the original framework structure of CFP,but also increase more active sites.The characterization results show that the CFP-200 sample obtained via heat treatment at 200℃for 2 h under N2 atmosphere has the highest Co3+/Co2+ratio.As an oxygen evolution reaction electrocatalyst,CFP-200 shows the best electrocatalytic activity among all samples.In 1.0 mol/L KOH electrolyte,the overpotential is 312 mV at a current density of 10 mA/cm2.Therefore,low-temperature heat treatment provides an effective method for preparing low-cost and high-efficiency electrocatalysts.
文献关键词:
作者姓名:
Wenhui Hu;Mingbo Zheng;Huiyu Duan;Wei Zhu;Ying Wei;Yi Zhang;Kunming Pan;Huan Pang
作者机构:
School of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou 225002,China;College of Materials Science and Technology,Nanjing University of Aeronautics and Astronautics,Nanjing 210016,China;National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials,and Henan Key Laboratory of High-temperature Structural and Functional Materials,Henan University of Science and Technology,Luoyang 471003,China
引用格式:
[1]Wenhui Hu;Mingbo Zheng;Huiyu Duan;Wei Zhu;Ying Wei;Yi Zhang;Kunming Pan;Huan Pang-.Heat treatment-induced Co3+enrichment in CoFePBA to enhance OER electrocatalytic performance)[J].中国化学快报(英文版),2022(03):1412-1416
A类:
Co3+enrichment,CoFePBA,Co3+is,Co2+ratio
B类:
Heat,treatment,induced,enhance,OER,electrocatalytic,performance,Increasing,active,metal,sites,valid,approach,improve,activity,this,research,through,partial,CFP,via,low,temperature,heat,effective,control,has,been,achieved,transformation,strategy,can,not,only,maintain,original,framework,structure,but,also,increase,more,characterization,results,that,obtained,under,N2,atmosphere,highest,oxygen,evolution,reaction,shows,best,among,all,samples,KOH,electrolyte,overpotential,mV,current,density,mA,Therefore,provides,method,preparing,cost,efficiency,electrocatalysts
AB值:
0.476614
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