典型文献
Promotion of the oxygen evolution performance of Ni-Fe layered hydroxides via the introduction of a proton-transfer mediator anion
文献摘要：
Developing efficient catalysts with high durability and activity for the oxygen evolution reaction(OER)is imperative for sustainable energy conversion technologies,including hydrogen generation and CO2 reduction,as well as other electrochemical energy storage systems.To this end,a comprehensive understanding of the mechanism for the water oxidation reaction is vital.Herein,a surfactant,nonafluoro-1-butanesulfonate(FBS),was introduced into Ni-Fe layered double hydroxide(NiFe-FBS/CFP)via electrochemical deposition on the surface of a carbon fiber paper(CFP)substrate.The as-prepared NiFe-FBS/CFP electrode exhibited excellent catalytic activities for OER compared to the Ni-Fe layered double hydroxide based electrode(NiFe-LDH/CFP),an excellent stability of 15 h,and an ultralow Tafel slope of 25.8 mV dec-1.Furthermore,by combining the results of pH-dependent kinetics investigations,chemical probing,proton inventory studies,and isotopic and atom-proton-transfer measurements,it was observed that a proton-transfer process controls the reaction rates of both the NiFe-LDH and NiFe-FBS catalysts,and the residual sulfonate groups serve as proton transfer mediator to accelerate the proton transfer rate.
文献关键词：
中图分类号：
作者姓名：
Wenlong Li;Fusheng Li;Yilong Zhao;Chang Liu;Yingzheng Li;Hao Yang;Ke Fan;Peili Zhang;Yu Shan;Licheng Sun
作者机构：
State Key Laboratory of Fine Chemicals,Institute of Artificial Photosynthesis,DUT-KTH Joint Education and Research Centre on Molecular Devices,Dalian University of Technology,Dalian 116024,China;Department of Chemistry,School of Engineering Sciences in Chemistry,Biotechnology and Health,KTH Royal Institute of Technology,Stockholm 10044,Sweden;Center of Artificial Photosynthesis for Solar Fuels,School of Science,Westlake University,Hangzhou 310024,China
文献出处：
引用格式：
[1]Wenlong Li;Fusheng Li;Yilong Zhao;Chang Liu;Yingzheng Li;Hao Yang;Ke Fan;Peili Zhang;Yu Shan;Licheng Sun-.Promotion of the oxygen evolution performance of Ni-Fe layered hydroxides via the introduction of a proton-transfer mediator anion)[J].中国科学:化学（英文版）,2022(02):382-390
A类：
nonafluoro,butanesulfonate
B类：
Promotion,oxygen,evolution,performance,layered,hydroxides,via,introduction,proton,transfer,mediator,anion,Developing,efficient,catalysts,high,durability,activity,reaction,OER,imperative,sustainable,energy,conversion,technologies,including,hydrogen,generation,reduction,well,other,electrochemical,storage,systems,To,this,comprehensive,understanding,mechanism,water,oxidation,vital,Herein,surfactant,FBS,was,introduced,into,double,NiFe,CFP,deposition,surface,carbon,fiber,paper,substrate,prepared,electrode,exhibited,excellent,catalytic,activities,compared,LDH,stability,ultralow,Tafel,slope,mV,dec,Furthermore,by,combining,results,dependent,kinetics,investigations,probing,inventory,studies,isotopic,atom,measurements,observed,that,process,controls,rates,both,residual,groups,accelerate
AB值：
0.540802
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