典型文献
Engineering zirconium-based metal-organic framework-801 films on carbon cloth as shuttle-inhibiting interlayers for lithium-sulfur batteries
文献摘要：
Lithium-sulfur batteries have been regarded as the next-generation rechargeable batteries due to their high theoretical energy density and specific capacity.Never-theless,the shuttle effect of lithium polysulfides has hindered the development of lithium-sulfur batteries.Herein,a novel zirconium-based metal-organic frame-work-801 film on carbon cloth was developed as a versatile interlayer for lithium-sulfur batteries.This interlayer has a hierarchical porous structure,suitable for the immobiliza-tion of lithium polysulfides and accommodating volume expansion on cycling.Moreover,the MOF-801 material is capable of strongly adsorbing lithium polysulfides and promoting their catalytic conversion,which can be enhanced by the abundant active sites provided by the continuous structure of the MOF-801 films.Based on the above advantages,the lithium-sulfur battery,with the proposed interlayer,delivers an initial discharge capacity of 927 mAh·g-1 at 1 C with an extremely low decay rate of 0.04％over 500 cycles.Additionally,a high area capacity of 4.3 mAh·cm-2 can be achieved under increased S loading.
文献关键词：
中图分类号：
作者姓名：
Gaofeng Jin;Jiale Zhang;Baoying Dang;Feichao Wu;Jingde Li
作者机构：
Hebei Provincial Key Laboratory of Green Chemical Technology and High Efficient Energy Saving,Tianjin Key Laboratory of Chemical Process Safety,School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China
文献出处：
引用格式：
[1]Gaofeng Jin;Jiale Zhang;Baoying Dang;Feichao Wu;Jingde Li-.Engineering zirconium-based metal-organic framework-801 films on carbon cloth as shuttle-inhibiting interlayers for lithium-sulfur batteries)[J].化学科学与工程前沿,2022(04):511-522
A类：
immobiliza
B类：
Engineering,zirconium,metal,organic,framework,films,carbon,cloth,shuttle,inhibiting,interlayers,lithium,sulfur,batteries,Lithium,have,been,regarded,next,generation,rechargeable,due,their,high,theoretical,energy,density,specific,capacity,Never,theless,effect,polysulfides,has,hindered,development,Herein,novel,was,developed,versatile,This,hierarchical,porous,structure,suitable,accommodating,volume,expansion,cycling,Moreover,MOF,material,capable,strongly,adsorbing,promoting,catalytic,conversion,which,can,enhanced,by,abundant,active,sites,provided,continuous,Based,above,advantages,battery,proposed,delivers,initial,discharge,mAh,extremely,low,decay,rate,cycles,Additionally,area,achieved,under,increased,loading
AB值：
0.558294
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