典型文献
Facile synthesis of KVPO4F/reduced graphene oxide hybrid as a high-performance cathode material for potassium-ion batteries
文献摘要:
Potassium-ion batteries(PIBs)as a substitute for lithium-ion batteries have aroused widespread atten-tion and have been rapidly developed.In the positive electrode materials,polyanionic compound has a high working voltage and large reversible capacity on account of its distinct framework and the strong inducing effect of the anionic group.Herein,a KVPO4F/reduced graphene oxide(KVPF/rGO)hybrid was fabricated via a simple multi-step approach as the polyanionic cathode material for PIBs.Profiting from the small size of KVPF nanoparticles and their uniform distribution in the rGO framework,the as-synthesized KVPF/rGO hybrid manifests a large discharge capacity of 103.2 mAh g-1 with an outstanding energy density of 436.5 Wh kg-1.Through rGO decoration,the hybrid also demonstrates remarkable rate and cycling properties.By employing ex-situ X-ray diffraction(XRD)and X-ray photoelectron spec-troscopy(XPS)techniques,the potassium storage mechanism of KVPF was clearly revealed.The facile preparation procedure and superior properties endow it great application prospects in large-scale energy storage.
文献关键词:
中图分类号:
作者姓名:
Jianzhi Xu;Jiaying Liao;Yifan Xu;Jianbo Li;Chuannan Zhu;Jun Lin;Xiaosi Zhou
作者机构:
Jiangsu Key Laboratory of New Power Batteries,Jiangsu Collaborative Innovation Center of Biomedical Functional Materials,School of Chemistry and Materials Science,Nanjing Normal University,Nanjing 210023,Jiangsu,China
文献出处:
引用格式:
[1]Jianzhi Xu;Jiaying Liao;Yifan Xu;Jianbo Li;Chuannan Zhu;Jun Lin;Xiaosi Zhou-.Facile synthesis of KVPO4F/reduced graphene oxide hybrid as a high-performance cathode material for potassium-ion batteries)[J].能源化学,2022(05):284-292
A类:
KVPO4F,polyanionic,KVPF
B类:
Facile,synthesis,reduced,graphene,oxide,hybrid,high,performance,cathode,potassium,batteries,Potassium,PIBs,substitute,lithium,have,aroused,widespread,atten,been,rapidly,developed,In,positive,electrode,materials,compound,has,working,voltage,large,reversible,capacity,account,its,distinct,framework,strong,inducing,effect,group,Herein,rGO,was,fabricated,via,simple,multi,step,approach,Profiting,from,small,nanoparticles,their,uniform,distribution,synthesized,manifests,discharge,mAh,outstanding,energy,density,Wh,Through,decoration,also,demonstrates,remarkable,cycling,properties,By,employing,ex,situ,ray,diffraction,photoelectron,troscopy,XPS,techniques,storage,mechanism,clearly,revealed,facile,preparation,procedure,superior,endow,great,application,prospects,scale
AB值:
0.580371
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