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典型文献
Plasma-induced ε-MnO2 based aqueous zinc-ion batteries and their dissolution-deposition mechanism
文献摘要:
MnO2 has attracted great interest in working as the cathode of zinc ion batteries.However,the develop-ment of high-capacity,high-energy-density,and durable manganese-based cathodes with an easy synthe-sis strategy and proper energy storage mechanism remains an ongoing challenge.Herein,a facile plasma-induced strategy was demonstrated to introduce oxygen vacancies into the ε-MnO2,and the obtained oxygen vacancies-rich ε-MnO2 nanosheets(ε-MnO2-x)show satisfactory electrochemical performances.Furthermore,an appropriate energy storage mechanism for dissolution/deposition was proposed.Thanks to a synergistic effect of the oxygen vacancies in ε-Mn02 nanosheets and the exposed free-standing col-lector for Mn2+dissolution/deposition,the ε-MnO2-x nanosheets electrode delivers a remarkable capac-ity(337 mAh g-1 at 0.1 A g-1)and exhibits an ultrahigh energy density of 462 Wh kg-1(based on the weights of the cathode active material).Furthermore,impressive durability with 85.9%capacity retention after 1000 cycles was obtained.The superior electrochemical performance makes the plasma-induced strategy promising for designing advanced metal oxide electrode materials for high-performance aqueous zinc ion batteries.
文献关键词:
作者姓名:
Le Zhang;Shuhua Yang;Wenqing Fu;Yanwei Cui;Jieqiang Wang;Degang Zhao;Chao Yang;Xiutong Wang;Bingqiang Cao
作者机构:
Materials Center for Energy and Photoelectrochemical Conversion,School of Material Science and Engineering,University of Jinan,Jinan 250022,China;School of Physics and Physical Engineering,Qufu Normal University,Qufu 273165,China;Key Laboratory of Marine Environmental Corrosion and Bio-fouling,Institute of Oceanology and Center for Ocean Mega-Science,Chinese Academy of Sciences,Qingdao 266071,China
引用格式:
[1]Le Zhang;Shuhua Yang;Wenqing Fu;Yanwei Cui;Jieqiang Wang;Degang Zhao;Chao Yang;Xiutong Wang;Bingqiang Cao-.Plasma-induced ε-MnO2 based aqueous zinc-ion batteries and their dissolution-deposition mechanism)[J].材料科学技术(英文版),2022(32):206-213
A类:
lector,Mn2+dissolution
B类:
Plasma,induced,MnO2,aqueous,zinc,batteries,their,deposition,mechanism,has,attracted,great,interest,working,However,develop,ment,capacity,energy,density,durable,manganese,cathodes,easy,synthe,sis,strategy,proper,storage,remains,ongoing,challenge,Herein,facile,plasma,was,demonstrated,introduce,oxygen,vacancies,into,obtained,rich,nanosheets,show,satisfactory,electrochemical,performances,Furthermore,appropriate,proposed,Thanks,synergistic,effect,Mn02,exposed,free,standing,col,electrode,delivers,remarkable,mAh,exhibits,ultrahigh,Wh,weights,active,impressive,durability,retention,after,cycles,superior,makes,promising,designing,advanced,metal,oxide,materials
AB值:
0.522316
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