典型文献
Anion effect on Li/Na/K hybrid electrolytes for Graphite//NCA(LiNi0.8Co0.15Al0.05O2) Li-ion batteries
文献摘要：
The electrolyte is an essential component of a battery system since it is responsible for the conduction of ions between the electrodes.In the quest for cheaper alternatives to common organic electrolytes for lithium-ion batteries (LIB),we formulated hybrid electrolytes comprising a mixture of Na,K,and Li alka-line salts with ethylene carbonate (EC),ethyl methyl carbonate (EMC),and lithium hexafluorophosphate(LiPF6),giving a total salt concentration of 1.5 M;we determined their physicochemical properties and investigated their electrochemical behavior on a nickel cobalt aluminum oxide (NCA) cathode and gra-phite (Gr) anode.The electrolytes demonstrated a melting transition peak (Tm),eutectic behavior,and ionic conductivities (～13 mS cm-1) close to those of a commercial LIB electrolyte (SE,EC/EMC + 1 M LiPF6) and activation energies of ca.3 kJ mol-1.The half-cell coin cells revealed high coulombic efficiency(99％),specific capacity (175 mAh g-1 at C/10),and capacity retention (92％ for NaCF3SO3) for the NC.A cathode and a moderate performance (coulombic efficiency of 98％ for 20 cycles) on the graphite anode after the formation of the SEI layer.The hybrid electrolytes were cycled at 25 ℃ in a Gr//NCA cell yielding specific capacities of ca.225 mAh g-1 at a C/5 rate,corroborating that the anion plays a key role and high-lighting their potential for energy storage applications.
文献关键词：
中图分类号：
作者姓名：
Aiman Jrondi;Georgios Nikiforidis;Mérièm Anouti
作者机构：
Laboratoire PCM2E,Université de Tours,Faculté des sciences et technologie,Parc de Grandmont,37200 Tours,France;LE STUDIUM Institute for Advanced Studies,45000 Orléans,France
文献出处：
引用格式：
[1]Aiman Jrondi;Georgios Nikiforidis;Mérièm Anouti-.Anion effect on Li/Na/K hybrid electrolytes for Graphite//NCA(LiNi0.8Co0.15Al0.05O2) Li-ion batteries)[J].能源化学,2022(01):451-462
A类：
hexafluorophosphate,phite,NaCF3SO3
B类：
Anion,effect,hybrid,electrolytes,Graphite,NCA,LiNi0,8Co0,15Al0,05O2,batteries,essential,component,battery,system,since,responsible,conduction,between,electrodes,In,quest,cheaper,alternatives,common,organic,lithium,LIB,formulated,comprising,mixture,alka,line,salts,ethylene,carbonate,EC,methyl,EMC,LiPF6,giving,total,concentration,determined,their,physicochemical,properties,investigated,electrochemical,behavior,nickel,cobalt,aluminum,oxide,cathode,anode,demonstrated,melting,transition,peak,Tm,eutectic,ionic,conductivities,mS,close,those,commercial,activation,energies,kJ,half,coin,cells,revealed,high,coulombic,efficiency,specific,capacity,mAh,retention,moderate,performance,cycles,graphite,after,formation,SEI,layer,were,cycled,yielding,capacities,corroborating,that,anion,plays,key,role,lighting,potential,energy,storage,applications
AB值：
0.578691
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