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典型文献
Improvement of stability and solid-state battery performances of annealed 70Li2S-30P2S5 electrolytes by additives
文献摘要:
The replacement of liquid electrolyte with solid electrolyte can significantly improve the safety and power/energy density of lithium batteries.70Li2S-30P2S5 is one of the most promising solid electrolytes with high con-ductivity for solid-state batteries.In this work,the ionic conductivity and stability toward moisture and lithium metal of 70Li2S-30P2S5 were enhanced by introducing the different amounts of Li2O additives.65Li2S-30P2S5-1%Li2O delivered the highest conductivity,while 65Li2S-30P2S5-5%Li2O showed the best moisture stability and improved lithium compatibility.Solid-state batteries using 65Li2S-30P2S5-5%Li2O electrolyte and high-voltage LiNi0.6Mn0.2Co0.2O2 cathode exhibited low initial dis-charge capacity (100 mAh·g-1) and Coulombic efficiency(69%).Li3InC16 electrolytes were introduced both in the cathode mixture to replace sulfide electrolyte and in the interface layer to improve the cathode compatibility for the solid-state batteries,showing enhanced discharge capacity(175 mAh·g-1) and improved initial Coulombic efficiency(86%).Moreover,it also exhibited good performance at-20 ℃.
文献关键词:
作者姓名:
Hao-Tian Ren;Zi-Qi Zhang;Jun-Zhao Zhang;Lin-Feng Peng;Zhen-Yuan He;Ming Yu;Chuang Yu;Long Zhang;Jia Xie;Shi-Jie Cheng
作者机构:
State Key Laboratory of Advanced Electromagnetic Engineering and Technology,School of Electrical and Electronic Engineering,Huazhong University of Science and Technology,Wuhan 430074,China;Clean Nano Energy Center,State Key Laboratory of Metastable Materials Science and Technology,Yanshan University,Qinhuangdao 066004,China;School of Physics,Huazhong University of Science and Technology,Wuhan 430074,China;Wuhan National High Magnetic Field Center and School of Physics,Huazhong University of Science and Technology,Wuhan 430074,China
引用格式:
[1]Hao-Tian Ren;Zi-Qi Zhang;Jun-Zhao Zhang;Lin-Feng Peng;Zhen-Yuan He;Ming Yu;Chuang Yu;Long Zhang;Jia Xie;Shi-Jie Cheng-.Improvement of stability and solid-state battery performances of annealed 70Li2S-30P2S5 electrolytes by additives)[J].稀有金属(英文版),2022(01):106-114
A类:
70Li2S,30P2S5,65Li2S,Li3InC16
B类:
Improvement,stability,solid,state,battery,performances,annealed,electrolytes,by,additives,replacement,liquid,significantly,safety,power,energy,density,lithium,batteries,one,most,promising,this,work,ionic,conductivity,toward,moisture,metal,were,enhanced,introducing,different,amounts,Li2O,delivered,highest,while,showed,best,improved,compatibility,Solid,using,voltage,LiNi0,6Mn0,2Co0,2O2,cathode,exhibited,low,initial,capacity,mAh,Coulombic,efficiency,introduced,both,mixture,sulfide,interface,layer,showing,discharge,Moreover,also,good
AB值:
0.414269
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