典型文献
Electrochemical dual-oxidation strategy enables access to α-chlorosulfoxides from sulfides
文献摘要：
Electrochemistry contributes a strong tool for the manufacture of molecules,addressing intractable chal-lenges in synthetic chemistry by enabling innovative reaction pathways.Herein,a bifunctional reagent,aqueous hydrochloric acid,is used to establish an electrochemical selective dual-oxidation approach that gives access to α-chlorosulfoxides from sulfides.This strategy presents broad substrate scope,high diastereoselectivity,and regioselectivity.The late-stage modification of amino acids and pharmaceutical derivatives further highlights the utility.Furthermore,detailed mechanistic studies reveal that the key success for this selective chemical transformation is the dual-oxidation process at the anode.This elec-trochemical dual-oxidation strategy may have wide universality;we anticipate diverse applications of this protocol across the many fields of chemistry.
文献关键词：
中图分类号：
作者姓名：
Huamin Wang;Mingming Yu;Panyue Zhang;Hao Wan;Hengjiang Cong;Aiwen Lei
作者机构：
The Institute for Advanced Studies (IAS),College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,China;National Research Center for Carbohydrate Synthesis,Jiangxi Normal University,Nanchang 330022,China;Department of Chemical and Materials Engineering,King Abdulaziz University,Jeddah 21589,Saudi Arabia
文献出处：
引用格式：
[1]Huamin Wang;Mingming Yu;Panyue Zhang;Hao Wan;Hengjiang Cong;Aiwen Lei-.Electrochemical dual-oxidation strategy enables access to α-chlorosulfoxides from sulfides)[J].科学通报（英文版）,2022(01):79-84
A类：
chlorosulfoxides,Electrochemistry
B类：
Electrochemical,dual,oxidation,strategy,enables,access,from,sulfides,contributes,strong,tool,manufacture,molecules,addressing,intractable,chal,lenges,synthetic,by,enabling,innovative,reaction,pathways,Herein,bifunctional,reagent,aqueous,hydrochloric,used,establish,electrochemical,selective,approach,that,gives,This,presents,broad,substrate,scope,diastereoselectivity,regioselectivity,late,stage,modification,amino,acids,pharmaceutical,derivatives,further,highlights,utility,Furthermore,detailed,mechanistic,studies,reveal,key,success,this,transformation,process,anode,may,have,wide,universality,we,anticipate,diverse,applications,protocol,across,many,fields
AB值：
0.672927
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