典型文献
Direct methanol fuel cells system-A review of dual-role electrocatalysts for oxygen reduction and methanol oxidation
文献摘要:
One fundamental challenge in exploiting direct methanol fuel cells(DMFCs)is the preparation of inex-pensive,high active electrocatalysts,which are highly active and durable for the two half-reactions,i.e.,the methanol oxidation reaction(MOR)at the anode and the oxygen reduction reaction(ORR)at the cathode.Platinum group metals-based catalysts have been known the governing dual-functional electro-catalysts based on the literature reports.But these catalysts are expensive and commercialize the DMFC less attractive.In addition to the high-cost,there are also methanol crossover,CO poisoning,long-term instability,and other problems as for Pt-based spurs.For the dual-role MOR&ORR catalysts,methanol crossover is inevitable to a certain extent on the current development of DMFC with losses in terms of cell voltage.In this regard,one strategy is to exploit high selective anodic/cathodic electrocatalysts to cap-italize the energy density at a high concentration of methanol.According to the summary results,there are mainly two types of dual-role electrocatalysts:one is Pt-support/co-catalyst(designated as P-S/C)for MOR/ORR,the other is catalyst/co-catalyst(designated as C/C)for MOR/ORR.This paper aims to review the design and construction of the various dual-role catalysts and give some discussion briefly.
文献关键词:
中图分类号:
作者姓名:
Yuanhui Zuo;Wenchao Sheng;Wenquan Tao;Zhuo Li
作者机构:
College of Environment Science and Engineering,Tongji University,Shanghai 200092,China
文献出处:
引用格式:
[1]Yuanhui Zuo;Wenchao Sheng;Wenquan Tao;Zhuo Li-.Direct methanol fuel cells system-A review of dual-role electrocatalysts for oxygen reduction and methanol oxidation)[J].材料科学技术(英文版),2022(19):29-41
A类:
pensive,italize
B类:
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AB值:
0.490324
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