典型文献
Redox mediators for high-performance lithium-oxygen batteries
文献摘要:
Aprotic lithium-oxygen(Li-O2)batteries are receiving intense research interest by virtue of their ultra-high theoretical specific energy.However,current Li-O2 batteries are suffering from severe barriers,such as sluggish reaction kinetics and undesired parasitic reactions.Recently,molecular catalysts,i.e.redox mediators(RMs),have been explored to catalyse the oxygen electrochemistry in Li-O2 batteries and are regarded as an advanced solution.To fully unlock the capability of Li-O2 batteries,an in-depth understanding of the catalytic mechanisms of RMs is necessary.In this review,we summarize the working principles of RMs and their selection criteria,highlight the recent significant progress of RMs and discuss the critical scientific and technical challenges on the design of efficient RMs for next-generation Li-O2 batteries.
文献关键词:
中图分类号:
作者姓名:
Yaying Dou;Zhaojun Xie;Yingjin Wei;Zhangquan Peng;Zhen Zhou
作者机构:
Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education,School of Chemical Engineering,Zhengzhou University,Zhengzhou 450001,China;Institute of New Energy Material Chemistry,School of Materials Science and Engineering,Nankai University,Tianjin 300350,China;Key Laboratory of Physics and Technology for Advanced Batteries(Ministry of Education),College of Physics,Jilin University,Changchun 130012,China;Laboratory of Advanced Spectro-electrochemistry and Li-ion Batteries,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China
文献出处:
引用格式:
[1]Yaying Dou;Zhaojun Xie;Yingjin Wei;Zhangquan Peng;Zhen Zhou-.Redox mediators for high-performance lithium-oxygen batteries)[J].国家科学评论(英文版),2022(04):143-162
A类:
Aprotic
B类:
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AB值:
0.629
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