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典型文献
Decorating Covalent Organic Frameworks with High-density Chelate Groups for Uranium Extraction
文献摘要:
The extraction of uranium from aqueous solution is highly desirable for sustaining the increasing demand for environmental safety and nuclear fuel.Herein,we report a strategy using a two-step covalent modification for the synthesis of covalent organic frameworks(COFs)with high-density amidoxime chelate groups at periphery.The introduction of dense amidoxime groups plays a pivotal role in uranium adsorption.The resulting COF exhibits strong affinity with the distribution coefficient of 5.2x104 mL/g and a high adsorption capacity of 319.9 mg/g.The strategy could be expanded to identify and remove different contaminants by introducing special functional groups.
文献关键词:
作者姓名:
QIN Xudong;TANG Xiaohui;MA Yu;XU Hong;XU Qing;YANG Weiting;GU Cheng
作者机构:
State Key Laboratory of Luminescent Materials and Devices,Institute of Polymer Optoelectronic Materials and Devices,South China University of Technology,Guangzhou 510640,P.R.China;Key Laboratory of Advanced Materials of Tropical Island Resources,Ministry of Eduction,School of Chemical Engineering and Technology,Hainan University,Haikou 570228,P.R.China;Institute of Nuclear and New Energy Technology,Tsinghua University,Beijing 100084,P.R.China;CAS Key Laboratory of Low-Carbon Conversion Science and Engineering,Shanghai Advanced Research Institute(SARI),Chinese Academy of Sciences(CAS),Shanghai 201210,P.R.China;Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates,South China University of Technology,Guangzhou 510640,P.R.China
引用格式:
[1]QIN Xudong;TANG Xiaohui;MA Yu;XU Hong;XU Qing;YANG Weiting;GU Cheng-.Decorating Covalent Organic Frameworks with High-density Chelate Groups for Uranium Extraction)[J].高等学校化学研究(英文版),2022(02):433-439
A类:
Chelate,2x104
B类:
Decorating,Covalent,Organic,Frameworks,High,density,Groups,Uranium,Extraction,extraction,uranium,from,aqueous,solution,highly,desirable,sustaining,increasing,demand,environmental,safety,nuclear,fuel,Herein,we,report,strategy,using,two,step,covalent,modification,synthesis,organic,frameworks,COFs,amidoxime,chelate,groups,periphery,introduction,dense,plays,pivotal,role,adsorption,resulting,exhibits,strong,affinity,distribution,coefficient,capacity,could,be,expanded,identify,remove,different,contaminants,by,introducing,special,functional
AB值:
0.700042
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