典型文献
Graphene-Coated 1D MoTe2 Nanorods as Anode for Enhancing Lithium-Ion Battery Performance
文献摘要:
One-dimensional nanostructures(1D)with short ion diffusion distance and fast ion transport path are excellent for lithium-ion batteries(LIBs).However,the nature of layered transition metal dichalcogenides makes it difficult to form 1D nanohybrids.Here,the MoTe2 nanorods with an av-erage diameter of 100-200 nm and length of 1-3 μm encapsulated by reduced graphene oxide(MoTe2/rGO)have been fabricated via in-situ reaction of GO coated Mo3O10(C2H10N2)nanowires with Te under Ar/H2 atmosphere.When applied as anode of LIBs,the MoTe2/rGO delivers a high reversible capacity(637 mA h g-1 after 100 cycles at0.2 A g-1),good rate capability(374 mA h g-1 at 2 A g-1)and excellent stability(360 mA h g-1 after 200 cycles at 0.5 A g-1),which surpasses bare MoTe2 nanorods and bulk MoTe2 crystallite.Furthermore,a lithium-ion full cell constructed by coupling MoTe2/rGO anode and LiCoO2 cathode shows a capacity of 105 mA h g-1 at 0.1 C.The enhanced performance mainly benefits from the ad-vantages of 1D nanostructure,and meanwhile the rGO thin layers are able to improve the conductivity and maintain the structural stability.This work provides a simple pathway for the synthesis of 1D TMDs nanostructures for energy storage and conversion.
文献关键词:
中图分类号:
作者姓名:
Shuwei Chai;Xiong Xiao;Yabei Li;Changhua An
作者机构:
Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion,School of Chemistry and Chemical Engineering,and Tianjin Key Laboratory of Advanced Functional Porous Materials,Institute for New Energy Materials&Low-Carbon Technologies,Tianjin University of Tech-nology,Tianjin 300384,China
文献出处:
引用格式:
[1]Shuwei Chai;Xiong Xiao;Yabei Li;Changhua An-.Graphene-Coated 1D MoTe2 Nanorods as Anode for Enhancing Lithium-Ion Battery Performance)[J].结构化学,2022(08):18-24
A类:
Mo3O10,C2H10N2,at0
B类:
Graphene,Coated,1D,MoTe2,Nanorods,Anode,Enhancing,Lithium,Ion,Battery,Performance,One,dimensional,nanostructures,short,diffusion,distance,fast,transport,excellent,lithium,batteries,LIBs,However,nature,layered,transition,metal,dichalcogenides,makes,difficult,nanohybrids,Here,nanorods,erage,diameter,length,encapsulated,by,reduced,graphene,oxide,rGO,have,been,fabricated,via,situ,reaction,coated,nanowires,under,Ar,H2,atmosphere,When,applied,anode,delivers,high,reversible,capacity,mA,after,cycles,good,rate,capability,stability,which,surpasses,bare,bulk,crystallite,Furthermore,full,constructed,coupling,LiCoO2,cathode,shows,enhanced,performance,mainly,benefits,from,ad,vantages,meanwhile,thin,layers,able,improve,conductivity,maintain,structural,This,work,provides,simple,pathway,synthesis,TMDs,energy,storage,conversion
AB值:
0.613532
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