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典型文献
Optical,thermal,and mechanical properties of(Y,-xScx)2O3 transparent ceramics
文献摘要:
Sesquioxides such as Y2O3 and Sc2O3 are important optical materials,but the fabrication of their transparent ceramics remains a challenge due to the ultra-high melting point of over 2400℃.In this work,a series of(Y 1-xScx)2O3 transparent ceramics were successfully fabricated by a simple vacuum sintering process without any sintering additives,and the effect of scandium(Sc)content(x)on the crystal structure and optical/thermal/mechanical properties was evaluated.Y2O3 and Sc2O3 form a complete solid solution with a cubic bixbyite structure.The formation of(Y 1-xScx)2O3 solid solution promotes the densification of ceramics,leading to the realization of high transparency close to the theoretical transmittance over a wide wavelength range of 0.35-8 μm.In particular,the in-line transmittance in the range of 0.6-6 μm remains above 80%for(YY1-xScx)2O3 with x=0.23-0.31,while the pristine Y2O3 and Sc2O3 are opaque.Moreover,the mechanical properties including Vickers hardness(HV),fracture toughness(KIC),and biaxial flexural strength(δb)are evidently enhanced due to the solid solution strengthening,while the thermal conductivity(k)is reduced due to the reduction of photon free path.This study demonstrates that forming of solid solution is a facile and universal approach for preparing sesquioxide transparent ceramics with high optical and mechanical quality.
文献关键词:
作者姓名:
Changliang YANG;Jiquan HUANG;Qiufeng HUANG;Zhonghua DENG;Yun WANG;Xiaoyun LI;Zehua ZHOU;Jian CHEN;Zhuguang LIU;Wang GUO
作者机构:
College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350117,China;Key Laboratory of Optoelectronic Materials Chemistry and Physics,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China;Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China,Fuzhou 350108,China
引用格式:
[1]Changliang YANG;Jiquan HUANG;Qiufeng HUANG;Zhonghua DENG;Yun WANG;Xiaoyun LI;Zehua ZHOU;Jian CHEN;Zhuguang LIU;Wang GUO-.Optical,thermal,and mechanical properties of(Y,-xScx)2O3 transparent ceramics)[J].先进陶瓷(英文版),2022(06):901-911
A类:
xScx,Sesquioxides,bixbyite,sesquioxide
B类:
Optical,thermal,mechanical,properties,transparent,ceramics,such,Y2O3,Sc2O3,important,optical,materials,but,fabrication,their,remains,challenge,due,ultra,high,melting,point,In,this,work,series,were,successfully,fabricated,simple,vacuum,sintering,process,without,any,additives,effect,scandium,content,crystal,structure,was,evaluated,complete,solid,solution,cubic,formation,promotes,densification,leading,realization,transparency,close,theoretical,transmittance,wide,wavelength,range,particular,line,above,YY1,while,pristine,opaque,Moreover,including,Vickers,hardness,HV,fracture,toughness,KIC,biaxial,flexural,evidently,enhanced,strengthening,conductivity,reduced,reduction,photon,free,path,This,study,demonstrates,that,forming,facile,universal,approach,preparing,quality
AB值:
0.524368
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