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典型文献
One-dimensional Rhodium-nickel Alloy Assemblies with Nano-dendrite Subunits for Alkaline Methanol Oxidation
文献摘要:
The noble metal rhodium(Rh)nanostructures have wide applications in catalysis and electrocataly-sis.In this work,a series of RhNi alloy nanostructures with different Rh/Ni atomic ratios can be synthesized by one-step wet chemical method.By adjusting RhⅢ/NiⅡ feed ratio,high-quality one-dimensional Rh1Ni1 alloy nanodendrite assemblies(Rh1Ni1-NDs-As)can be synthesized selectively.Electrochemical measurements show that the introduction of Ni can enhance the electroactivity of Rh nanomaterials for methanol oxidation reaction(MOR)in alkaline media.For potential practical application,Rh1Ni1-NDs-As reveals improved electroactivity and durability for MOR compared to commercial Rh nanoparticle due to the particular morphology,Ni-doping,high electrochemical active area,and excellent anti-poison ability.Considering the facial synthesis and high electro-activity/durability,Rh1Ni1-NDs-As may be promising anode catalysts in direct methanol fuel cells.
文献关键词:
作者姓名:
Yue Zhao;Yachong Liu;Boqiang Miao;Yu Ding;Pujun Jin;Yu Chen
作者机构:
Key Laboratory of Macromolecular Science of Shaanxi Province,Shaanxi Key Laboratory for Advanced Energy Devices,School of Materials Science and Engineering,Shaanxi Normal University,Xi'an 710062,China
文献出处:
引用格式:
[1]Yue Zhao;Yachong Liu;Boqiang Miao;Yu Ding;Pujun Jin;Yu Chen-.One-dimensional Rhodium-nickel Alloy Assemblies with Nano-dendrite Subunits for Alkaline Methanol Oxidation)[J].结构化学,2022(04):40-45
A类:
Subunits,electrocataly,RhNi,Rh1Ni1,nanodendrite
B类:
One,dimensional,Rhodium,nickel,Alloy,Assemblies,Nano,Alkaline,Methanol,Oxidation,noble,metal,rhodium,nanostructures,have,wide,applications,catalysis,In,this,work,series,alloy,different,atomic,ratios,can,be,synthesized,by,one,step,wet,method,By,adjusting,feed,high,quality,assemblies,NDs,selectively,Electrochemical,measurements,show,that,introduction,enhance,electroactivity,nanomaterials,methanol,oxidation,reaction,MOR,alkaline,media,For,potential,practical,reveals,improved,durability,compared,commercial,nanoparticle,due,particular,morphology,doping,electrochemical,active,area,excellent,anti,poison,Considering,facial,synthesis,may,promising,catalysts,direct,fuel,cells
AB值:
0.582789
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