典型文献
Thermoelectric Properties of n-type Poly (nickel 1,1,2,2-ethenetetrathiolate) Prepared by a New One-step Solvothermal Method
文献摘要:
Poly(nickel 1,1,2,2-ethenetetrathiolate) (poly[Nax(Ni-ett)]) is one of the most promising n-type organic thermoelectric materials which can be used in wearable devices. However, the conventional solution method is time-consuming and the prepared poly[Nax(Ni-ett)] usually has poor crystallinity, which does not benefit for achieving high thermoelectric performance. Here, a new one-step solvothermal method under the high reaction temperature and high vapor pressure was developed to prepare poly[Nax(Ni-ett)] with a quite short period. The experimental results show crystallinity and electrical conductivity are greatly enhanced as compared with those prepared by conventional solution method. As a result, a maximum ZT value of 0.04 was achieved at 440 K, which is about four times of the polymer prepared by the conventional solution method. This study may provide a new route to enhance the TE properties of n-type organic thermoelectric materials.
文献关键词:
中图分类号:
作者姓名:
WANG Yijiang;YAO Qin;QU Sanyin;CHEN Lidong
作者机构:
State Key Laboratory of High Performance Ceramics and Superfine Microstructure,Shanghai Institute of Ceramics,Chinese Academy of Science,Shanghai 200050,China;University of Chinese Academy of Sciences,Beijing 100049,China;School of Physical Science and Technology,Shanghai Tech University,Shanghai 201210,China;CAS Key Laboratory of Mate-rials for Energy Conversion,Shanghai Institute of Ceramics,Chinese Academy of Science,Shanghai 200050,China
文献出处:
引用格式:
[1]WANG Yijiang;YAO Qin;QU Sanyin;CHEN Lidong-.Thermoelectric Properties of n-type Poly (nickel 1,1,2,2-ethenetetrathiolate) Prepared by a New One-step Solvothermal Method)[J].武汉理工大学学报(材料科学版)(英文版),2022(04):760-764
A类:
ethenetetrathiolate,Nax,ett
B类:
Thermoelectric,Properties,type,Poly,nickel,Prepared,by,New,One,step,Solvothermal,Method,one,most,promising,organic,thermoelectric,materials,which,can,used,wearable,devices,However,conventional,solution,method,consuming,prepared,usually,has,poor,crystallinity,does,not,benefit,achieving,high,performance,Here,new,solvothermal,under,reaction,temperature,vapor,pressure,was,developed,quite,short,period,experimental,results,show,electrical,conductivity,greatly,enhanced,compared,those,maximum,ZT,value,achieved,about,four,times,polymer,This,study,may,provide,route,TE,properties
AB值:
0.525914
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