典型文献
Electrooxidation-Induced C(sp3)-H/C(sp2)-H Radical-Radical Cross-Coupling between Xanthanes and Electron-Rich Arenes
文献摘要：
The arylation of C(sp3)-H bonds has been a priority research topic in organic synthesis.Minsici reactions have been the powerful methods for C(sp3)-C(sp2)bonds formation.Despite its mature development,the scopes of arenes are usually suitable for elec-tron-deficient heterocyclic compounds,rather than electron-rich arenes.Herein,we report an electrooxidation-induced alkylation of electron-rich arenes with H2 evolution under exogenous oxidant-free conditions,avoiding the utilization of metal catalysts.This pro-tocol is well performed with various electron-rich aniline derivatives and nitrogen-containing heterocyclic compounds.We anticipate that this electro-oxidative C(sp3)-H arylation represents an important expansion for the classic arenes alkylation,thereby proving an attractive strategy for the developments of radical cross-coupling chemistry.
文献关键词：
中图分类号：
作者姓名：
Yuwei Liang;Linbin Niu;Xing-An Liang;Shengchun Wang;Pengjie Wang;Aiwen Lei
作者机构：
College of Chemistry and Molecular Sciences,Institute for Advanced Studies(IAS),Wuhan University,Wuhan,Hubei 430072,China
文献出处：
引用格式：
[1]Yuwei Liang;Linbin Niu;Xing-An Liang;Shengchun Wang;Pengjie Wang;Aiwen Lei-.Electrooxidation-Induced C(sp3)-H/C(sp2)-H Radical-Radical Cross-Coupling between Xanthanes and Electron-Rich Arenes)[J].中国化学（英文版）,2022(12):1422-1428
A类：
Electrooxidation,Xanthanes,Arenes,Minsici
B类：
Induced,sp3,sp2,Radical,Cross,Coupling,between,Electron,Rich,arylation,bonds,has,been,priority,research,topic,organic,synthesis,reactions,have,powerful,methods,formation,Despite,its,mature,scopes,arenes,usually,suitable,deficient,heterocyclic,compounds,rather,electron,rich,Herein,report,electrooxidation,induced,alkylation,H2,evolution,under,exogenous,oxidant,free,conditions,avoiding,utilization,metal,catalysts,This,tocol,well,performed,various,aniline,derivatives,nitrogen,containing,We,anticipate,that,this,oxidative,represents,important,expansion,classic,thereby,proving,attractive,strategy,developments,radical,cross,coupling,chemistry
AB值：
0.620907
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