典型文献
Dimensional Reduction of Eu-Based Metal-Organic Framework as Catalysts for Oxidation Catalysis of C(sp3)-H Bond
文献摘要：
Developing new catalysts for highly selectivity and conversion of saturated C(sp3)-H bonds is of great significance.In order to obtain catalysts with high catalytic performance,six Eu-based MOFs with different structural characteristics were obtained by using europium ions and different organic acid ligands,namely Eu-1～Eu-6.Eu-1,Eu-2 and Eu-3 featured three-dimensional structures,while Eu-4 and Eu-5 featured two-dimensional structures.Differently,a one-dimensional chain structure of Eu-6 was obtained by changing the ligand.All the six MOFs were applied to the catalytic reaction of C(sp3)-H bond,and it was found that the catalytic effect was gradually en-hanced with the decrease of dimension and the increase of the size of channels.As expected,Eu-6 showed the highest selectivity(～99％)and conversion(～99％).Moreover,catalytic cycling and stability tests showed Eu-6 can be a reliable catalyst.
文献关键词：
中图分类号：
作者姓名：
Yin Zhang;Wei-Dong Yu;Cai-Feng Zhao;Jun Yan
作者机构：
Junior Education Department,Changsha Normal University,Changsha,Hunan 410100,China;College of Science,Hunan University of Technology and Business,Changsha,Hunan 410000,China;College of Chemistry and Chemical Engineering,Central South University,Changsha,Hunan 410000,China;Hunan Institute of Nuclear Agricultural Science and Space Breeding,Hunan Academy of Agricultural Science,Changsha,Hunan 410000,China
文献出处：
引用格式：
[1]Yin Zhang;Wei-Dong Yu;Cai-Feng Zhao;Jun Yan-.Dimensional Reduction of Eu-Based Metal-Organic Framework as Catalysts for Oxidation Catalysis of C(sp3)-H Bond)[J].中国化学（英文版）,2022(04):480-486
A类：
B类：
Dimensional,Reduction,Eu,Based,Metal,Organic,Framework,Catalysts,Oxidation,Catalysis,sp3,Bond,Developing,new,catalysts,highly,selectivity,conversion,saturated,bonds,great,significance,In,order,catalytic,performance,six,MOFs,different,structural,characteristics,were,obtained,by,using,europium,ions,organic,acid,ligands,namely,featured,three,dimensional,structures,while,two,Differently,one,chain,was,changing,All,applied,reaction,found,that,effect,gradually,hanced,decrease,increase,size,channels,expected,showed,highest,Moreover,cycling,stability,tests,be,reliable
AB值：
0.562293
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