典型文献
Small Molecule:Polymer Blends for N-type Organic Thin Film Transistors via Bar-coating in Air
文献摘要:
Fabricating n-type organic thin film transistors (OTFTs) based on small molecules via solution processing under atmospheric condi-tions remains challenging.Blending small molecules with polymer is an effective strategy to improve the solution processibility and air stability of the resulted devices.In this study,polystyrene was chosen to blend with n-type small molecule DPP1012-4F to en-hance the continuity of the semiconductor layer and maintain a favorable edge-on stacking of semiconductors.The introduction of high-boiling point 1-chloronaphthalene as a solvent additive in the blending system can reduce the grain boundary defects in the microscopic morphology.These changes in aggregation behavior are confirmed by X-ray diffraction,atomic force microscopy and polarized optical microscopy analyses.Via bar-coating of the semiconductor layers in air,the electron mobility of the resulted OTFTs under the optimal condition is 0.73 cm2·V-1·s-1,which is amongst the highest n-type small molecule-based OTFTs with active layers prepared in air up to now.These results show a great potential of the blending strategy in industrial roll-to-roll manufacture of high-mobility n-type OTFTs.
文献关键词:
中图分类号:
作者姓名:
Xiaoyu Liu;Yibo Shi;Qian Zhou;Jie Liu;Lang Jiang;Yang Han
作者机构:
School of Materials Science and Engineering and Tianjin Key Laboratory of Molecular Optoelectronic Science,Tianjin University,Tianjin 300072,China;Beijing National Laboratory for Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China
文献出处:
引用格式:
[1]Xiaoyu Liu;Yibo Shi;Qian Zhou;Jie Liu;Lang Jiang;Yang Han-.Small Molecule:Polymer Blends for N-type Organic Thin Film Transistors via Bar-coating in Air)[J].中国化学(英文版),2022(01):91-96
A类:
OTFTs,DPP1012,chloronaphthalene
B类:
Small,Molecule,Polymer,Blends,type,Organic,Thin,Film,Transistors,via,Bar,coating,Air,Fabricating,organic,thin,film,transistors,small,molecules,solution,processing,under,atmospheric,tions,remains,challenging,Blending,polymer,effective,strategy,improve,processibility,air,stability,resulted,devices,In,this,study,polystyrene,was,chosen,4F,hance,continuity,maintain,favorable,edge,stacking,semiconductors,introduction,boiling,point,solvent,additive,blending,system,can,reduce,grain,boundary,defects,microscopic,morphology,These,changes,aggregation,behavior,confirmed,by,ray,diffraction,atomic,force,microscopy,polarized,optical,analyses,Via,bar,layers,electron,mobility,optimal,condition,which,amongst,highest,active,prepared,up,now,results,show,great,potential,industrial,roll,manufacture
AB值:
0.609723
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