典型文献
High Strength and Stable Proton Exchange Membrane Based on Perfluorosulfonic Acid/Polybenzimidazole
文献摘要：
In this work,a series of high strength,thermal stable and antioxidant proton exchange membranes were designed with solution processible polybenzimidazole(PBI)as the matrix and perfluorosulfonic acid(PFSA)as the fortifier for proton exchange.Solution processible PBI was successfully synthesized by introducing 4,4'-dicarboxydiphenyl etherinto the molecular chains of PBI.PFSA/PBI composite membranes were obtained by solution blending and film casting.PBI and PFSA/PBI composite membranes exhibited greatly enhanced tensile strength and Young's modulus compared to PFSA.PFSA/PBI composite membranes are stable below 300℃which are suitable for practical application in proton exchange membrane fuel cells.The PFSA/PBI composite membranes show good dimensional stability with low water uptake and swelling rate.The PFSA/PBI composite membranes also exhibit excellent antioxidation stability with less than 5％initial mass loss over 1 20 h in Fenton reagent.The proton conductivity of PBI is greatly enhanced by blending with PFSA and the proton conductivities of the composite membranes are increased with the raise of PFSA content and temperature.This work offers valuable insights into the exploration of PBI based high-performance proton exchange membranes.
文献关键词：
中图分类号：
作者姓名：
Tang-Cheng Xu;Chang-Shui Wang;Zhao-Yu Hu;Jiao-Jiao Zheng;Shao-Hua Jiang;Shui-Jian He;Hao-Qing Hou
作者机构：
College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330022,China;Co-Innovation Center of Efficient Processing and Utilization of Forest Resources,College of Materials Science and Engineering,Nanjing Forestry University,Nanjing 210037,China
文献出处：
引用格式：
[1]Tang-Cheng Xu;Chang-Shui Wang;Zhao-Yu Hu;Jiao-Jiao Zheng;Shao-Hua Jiang;Shui-Jian He;Hao-Qing Hou-.High Strength and Stable Proton Exchange Membrane Based on Perfluorosulfonic Acid/Polybenzimidazole)[J].高分子科学（英文版）,2022(07):764-771
A类：
Perfluorosulfonic,Polybenzimidazole,processible,perfluorosulfonic,fortifier,dicarboxydiphenyl,etherinto
B类：
High,Strength,Stable,Proton,Exchange,Membrane,Based,Acid,In,this,work,series,high,strength,thermal,stable,antioxidant,proton,exchange,membranes,were,designed,solution,polybenzimidazole,PBI,matrix,acid,PFSA,Solution,was,successfully,synthesized,by,introducing,molecular,chains,composite,obtained,blending,film,casting,exhibited,greatly,enhanced,tensile,Young,modulus,compared,below,which,suitable,practical,application,fuel,cells,show,good,dimensional,stability,water,uptake,swelling,rate,also,excellent,antioxidation,less,than,initial,mass,loss,over,Fenton,reagent,conductivity,conductivities,increased,raise,content,temperature,This,offers,valuable,insights,exploration,performance
AB值：
0.454351
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