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典型文献
Investigation of High Catalyteal Durability for Porous Pt Films Deposited via Magnetron Sputtering
文献摘要:
Porous Pt thin films were prepared on carbon papers by a single-step ultra-high dc magnetron sputtering method to obtain ideal electrodes for proton exchange membrane fuel cells. The platinum loading of the electrocatalyst layer is controlled at about 0.1 mg·cm-2. Structural characteristics and catalytic activities of the films were analyzed by scanning electron microscopy, atomic force microscopy, X-ray diffraction, cyclic voltammetry, and stress durability testing methods. The effect of treatment conditions of a substrate on the structural and performance characteristics of the catalytic films was shown as well. Films produced on acid-treated carbon papers at the argon pressure of 0.01 mbar possessed a homogeneous, highly developed surface along with a porous structure. Compared to Pt/TCPW(Toray carbon papers soaked in ultrapure water) electrodes, the film obtained on the acid-treated substrate had a larger electrochemical surface area (163.33 m2·g-1) and exhibited better catalytic stability and durability due to a porous structure as a result of Pt particle accumulation.
文献关键词:
作者姓名:
LIU Guangquan;PENG Liping;FAN Long;WANG Jin;FU Yajun;XIONG Zhengwei;REN Xuetan;CAO Linhong;WU Weidong
作者机构:
School of Materials Science and Engineering,Southwest University of Science and Technology,Mianyang 621010,China;Science and Technology on Plasma Physics Laboratory,Research Center of Laser,Fusion,China Academy of Engineering Physics,Mianyang 621900,China;Collaborative Innovation Center of IFSA(CICIFSA),Shanghai Jiao Tong University,Shanghai 200240,China
引用格式:
[1]LIU Guangquan;PENG Liping;FAN Long;WANG Jin;FU Yajun;XIONG Zhengwei;REN Xuetan;CAO Linhong;WU Weidong-.Investigation of High Catalyteal Durability for Porous Pt Films Deposited via Magnetron Sputtering)[J].武汉理工大学学报(材料科学版)(英文版),2022(02):194-201
A类:
Catalyteal,TCPW,ultrapure
B类:
Investigation,High,Durability,Porous,Pt,Films,Deposited,via,Magnetron,Sputtering,thin,films,were,prepared,carbon,papers,by,single,step,dc,magnetron,sputtering,ideal,electrodes,proton,exchange,membrane,fuel,cells,platinum,loading,electrocatalyst,layer,controlled,about,Structural,characteristics,catalytic,activities,analyzed,scanning,electron,microscopy,atomic,force,diffraction,cyclic,voltammetry,stress,durability,testing,methods,effect,treatment,conditions,substrate,structural,performance,was,shown,well,produced,acid,treated,argon,pressure,mbar,possessed,homogeneous,highly,developed,surface,along,porous,structure,Compared,Toray,soaked,water,obtained,had,larger,electrochemical,area,exhibited,better,stability,due,result,particle,accumulation
AB值:
0.629722
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