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典型文献
Stabilized cathode/sulfide solid electrolyte interface via Li2ZrO3 coating for all-solid-state batteries
文献摘要:
High-capacity LiNi0.8Co0.1Mn0.1O2(NCM)cathode is essential for realizing high energy density all-solid-state lithium batteries.However,the space charge layer effect between NCM cathode and the commonly used sulfide solid electrolyte results in deterioration of the battery performance.In this work,a 10-nm electrochemical stable Li2ZrO3(LZO)layer was in situ coated on the sur-face of NCM particles through facile wet chemical method.The LZO coating layer is able to mitigate the side reactions at the electrode/electrolyte interface and enables fast lithium transport dynamics,significantly improving the battery performances.The all-solid-state lithium batteries with modified NCM cathode and Li6PS5Cl electrolyte deliver stable cyclic performance with capacity retention ratio of 72.2%at 0.1C for 300 cycles and 72.9%at 0.5C for 600 cycles under room temperature.This work provides a promising approach to achieve stable electrode/electrolyte interface and improve the cyclic performance of high energy density all-solid-state lithium batteries.
文献关键词:
作者姓名:
Chen Zhao;Zi-Qiang Liu;Wei Weng;Ming Wu;Xiao-Yan Yan;Jing Yang;Huan-Ming Lu;Xia-Yin Yao
作者机构:
School of Materials Science and Engineering,Taiyuan University of Science and Technology,Taiyuan 030024,China;Ningbo Institute of Materials Technology and Engineering,Chinese Academy of Sciences,Ningbo 315201,China;Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences,Beijing 100049,China
引用格式:
[1]Chen Zhao;Zi-Qiang Liu;Wei Weng;Ming Wu;Xiao-Yan Yan;Jing Yang;Huan-Ming Lu;Xia-Yin Yao-.Stabilized cathode/sulfide solid electrolyte interface via Li2ZrO3 coating for all-solid-state batteries)[J].稀有金属(英文版),2022(11):3639-3645
A类:
B类:
Stabilized,cathode,sulfide,solid,electrolyte,interface,via,Li2ZrO3,coating,all,state,batteries,High,capacity,LiNi0,8Co0,1Mn0,1O2,NCM,essential,realizing,high,energy,density,lithium,However,space,charge,layer,effect,between,commonly,used,results,deterioration,battery,In,this,work,electrochemical,stable,LZO,was,situ,coated,sur,particles,through,facile,wet,method,mitigate,side,reactions,electrode,enables,fast,transport,dynamics,significantly,improving,performances,modified,Li6PS5Cl,deliver,cyclic,retention,1C,cycles,under,room,temperature,This,provides,promising,approach,achieve,improve
AB值:
0.51892
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