典型文献
An asymmetric bilayer polymer-ceramic solid electrolyte for high-performance sodium metal batteries
文献摘要：
Manufacturing an excellent solid electrolyte compatible with a high-voltage cathode is viewed as a crit-ical tactic for improving the energy density of solid-state sodium-ion batteries(SSIBs).A novel asymmet-ric bilayer solid electrolyte of the PEO-SN-NaClO4|NZSP-NSO with an anti-reduction PEO-SN-NaClO4 layer close to the Na side is constructed by solution casting.The ionic conductivity is enhanced by using suc-cinonitrile(SN)in polyethylene oxide(PEO)polymer electrolyte.The anti-oxidation layer of Na3Zr2Si2PO12 with Na2SiO3(NZSP-NSO)is served as the support of the membrane on the cathode,which could improve the interface compatibility and electrochemical performance of SSIBs.The asymmetric bilayer solid electrolyte simultaneously features a wide electrochemical stability window(4.65 V vs.Na+/Na)and a high conductivity(2.68×10-4 S cm-1).Furthermore,the solid electrolyte demonstrates stable Na plating/stripping over 700 h and remarkably improves cycling stability in Na/Na3V2(P04)3 bat-teries with an ultra-high capacity retention of 99.6％after 100 cycles at 50℃and 0.5 C.This study pro-vides an effective strategy for designing asymmetric high sodium ion conductivity solid-state electrolytes for high-performance SSIBs.
文献关键词：
中图分类号：
作者姓名：
Han Wang;Yongjiang Sun;Qing Liu;Zhiyuan Mei;Li Yang;Lingyan Duan;Hong Guo
作者机构：
School of Materials and Energy,Yunnan University,Kunming 650091,Yunnan,China
文献出处：
引用格式：
[1]Han Wang;Yongjiang Sun;Qing Liu;Zhiyuan Mei;Li Yang;Lingyan Duan;Hong Guo-.An asymmetric bilayer polymer-ceramic solid electrolyte for high-performance sodium metal batteries)[J].能源化学,2022(11):18-25
A类：
SSIBs,cinonitrile
B类：
An,asymmetric,bilayer,polymer,ceramic,solid,high,performance,sodium,metal,batteries,Manufacturing,excellent,compatible,voltage,cathode,viewed,crit,tactic,improving,energy,density,state,novel,PEO,SN,NaClO4,NZSP,NSO,anti,reduction,close,side,constructed,by,solution,casting,ionic,conductivity,enhanced,using,suc,polyethylene,oxide,oxidation,Na3Zr2Si2PO12,Na2SiO3,served,support,membrane,which,could,interface,compatibility,electrochemical,simultaneously,features,wide,stability,window,Na+,Furthermore,demonstrates,stable,plating,stripping,over,remarkably,improves,cycling,Na3V2,P04,ultra,capacity,retention,after,cycles,This,study,vides,effective,strategy,designing,electrolytes
AB值：
0.493412
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