典型文献
Entropy engineering in CaZn2Sb2-YbMg2Sb2 Zintl alloys for enhanced thermoelectric performance
文献摘要:
The significant atomic disorder induced by entropy engi-neering can effectively suppress lattice thermal conductivity and improve thermoelectric performance.The variety of compositions of Zintl phases offers a wide range of possibil-ities for entropy engineering.Herein we successfully prepared a five-component solid solution(CaZn2Sb2)0.5(YbMg2Sb2)0.5 with a configurational entropy of~1.40R,where R is the gas constant.As a result,the room-temperature lattice thermal conductivity was only~0.68W·m-1·K-1,which is lower than that of all AM2Sb2 Zintl phases.Moreover,combined with the optimization of the carrier concentration by Ag doping at M site of AM2Sb2,a peak figure of merit(zT)value of~1.17 was achieved at 773 K for(CaZn1.997Ag0.003 Sb2)0.5(YbMg1.997Ag0.003Sb2)0.5.
文献关键词:
中图分类号:
作者姓名:
Ke-Jia Liu;Zong-Wei Zhang;Chen Chen;Li-Hua Wei;Huo-Lun He;Jun Mao;Qian Zhang
作者机构:
School of Materials Science and Engineering,and Institute of Materials Genome&Big Data,Harbin Institute of Technology,Shenzhen 518055,China;Department of Mechanical Engineering,The University of Hong Kong,Hong Kong 999077,China;State Key Laboratory of Advanced Welding and Joining,Harbin Institute of Technology,Harbin 150001,China
文献出处:
引用格式:
[1]Ke-Jia Liu;Zong-Wei Zhang;Chen Chen;Li-Hua Wei;Huo-Lun He;Jun Mao;Qian Zhang-.Entropy engineering in CaZn2Sb2-YbMg2Sb2 Zintl alloys for enhanced thermoelectric performance)[J].稀有金属(英文版),2022(09):2998-3004
A类:
CaZn2Sb2,YbMg2Sb2,40R,68W,AM2Sb2,CaZn1,997Ag0,YbMg1,003Sb2
B类:
Entropy,engineering,Zintl,alloys,enhanced,thermoelectric,performance,significant,atomic,disorder,induced,by,entropy,effectively,suppress,lattice,thermal,conductivity,improve,variety,compositions,phases,offers,wide,range,possibil,ities,Herein,successfully,prepared,five,component,solid,solution,configurational,where,gas,constant,result,room,temperature,was,only,which,lower,than,that,Moreover,combined,optimization,carrier,concentration,doping,site,peak,figure,merit,zT,value,achieved
AB值:
0.491887
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