典型文献
Fabrication of bimetallic Cu-Zn adsorbents with high dispersion by using confined space for gas adsorptive separation
文献摘要：
The number of active components and their-dispersion degree are two key factors affecting the performance of adsorbents.Here,we report a simple but efficient strategy for dispersing active components by using a confined space,which is formed by mesoporous silica walls and templates in the as-prepared SBA-15(AS).Such a confined space does not exist in the conventional support,calcined SBA-15,which does not contain a template.The Cu and Zn precursors were introduced to the confined space in the AS and were converted to CuO and ZnO during calcination,during which the template was also removed.The results show that up to 5 mmol-g1 of CuO and ZnO can be well dispersed;however,severe aggregation of both oxides takes place in the sample derived from the calcined SBA-15 with the same loading.Confined space in the AS and the strong interactions caused by the abundant hydroxyl groups are responsible for the dispersion of CuO and ZnO.The bimetallic materials were employed for the adsorptive separation of propene and propane.The samples prepared from the as-prepared SBA-15 showed superior performance to their counterparts from the calcined SBA-15 in terms of both adsorption capacity of propene and selectivity for propene/propane.
文献关键词：
中图分类号：
作者姓名：
Yu-Chao Wang;Tian-Tian Li;Li Huang;Xiao-Qin Liu;Lin-Bing Sun
作者机构：
State Key Laboratory of Materials-Oriented Chemical Engineering,Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM),College of Chemical Engineering,Nanjing Tech University,Nanjing 211816,China
文献出处：
引用格式：
[1]Yu-Chao Wang;Tian-Tian Li;Li Huang;Xiao-Qin Liu;Lin-Bing Sun-.Fabrication of bimetallic Cu-Zn adsorbents with high dispersion by using confined space for gas adsorptive separation)[J].化学科学与工程前沿,2022(11):1623-1631
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B类：
Fabrication,bimetallic,adsorbents,high,dispersion,by,using,confined,space,gas,adsorptive,separation,number,active,components,their,degree,two,key,factors,affecting,performance,Here,report,simple,but,efficient,strategy,dispersing,which,formed,mesoporous,silica,walls,templates,prepared,SBA,AS,Such,does,not,exist,conventional,support,calcined,contain,precursors,were,introduced,converted,CuO,ZnO,during,calcination,was,also,removed,results,that,g1,can,well,dispersed,however,severe,aggregation,both,oxides,takes,place,derived,from,same,loading,Confined,strong,interactions,caused,abundant,hydroxyl,groups,responsible,materials,employed,propene,propane,samples,showed,superior,counterparts,terms,adsorption,capacity,selectivity
AB值：
0.518728
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