典型文献
Lithium-based draw solute for forward osmosis to treat wastewater discharged from lithium-ion battery manufacturing
文献摘要:
As draw solute is the core element of forward osmosis(FO)technology,here Li-Bet-Tf2N synthesized from a customized ionic liquid betainium bis(trifluoro-methylsulfonyl)imide([Hbet][Tf2N])and Li2CO3 recov-ered from lithium-ion battery(LIB)wastes is proposed as a novel draw solute to treat Li+-containing wastewater from LIB manufacturing through FO filtration.Having high dissociation ability and an extended structure,Li-Bet-Tf2N generates a sufficiently high osmotic pressure to drive the FO filtration efficiently along with insignificant reverse solute diffusion.Li-Bet-Tf2N produces a water flux of 21.3 L·(m2·h)-1 at 1.0 mol·L-1 against deionized water,surpassing conventional NaCl and MgCl2 draw solutes with a higher water recovery efficiency and a smaller solute loss.Li-Bet-Tf2N induces a more stable and higher water permeation flux with a 10.0%water flux decline than NaCl and MgCl2 for which the water fluxes decline 16.7%and 16.4%,respectively,during the treatment of 2000 mg·L-1 Li+-containing wastewater for 12 h.More remarkably,unlike other draw solutes which require intensive energy input and complicated processes in recycling,Li-Bet-Tf2N is easily separated from water via solvent extraction.Reproducible results are achieved with the recycled Li-Bet-Tf2N.Li-Bet-Tf2N thus demon-strates a novel class of draw solute with great potentials to treat wastewater economically.
文献关键词:
中图分类号:
作者姓名:
Rongzhen Chen;Xinfei Dong;Qingchun Ge
作者机构:
College of Environment and Safety Engineering,Fuzhou University,Fuzhou 350116,China
文献出处:
引用格式:
[1]Rongzhen Chen;Xinfei Dong;Qingchun Ge-.Lithium-based draw solute for forward osmosis to treat wastewater discharged from lithium-ion battery manufacturing)[J].化学科学与工程前沿,2022(05):755-763
A类:
betainium,trifluoro,methylsulfonyl,Hbet
B类:
Lithium,draw,forward,osmosis,wastewater,discharged,from,lithium,battery,manufacturing,core,element,FO,technology,here,Bet,Tf2N,synthesized,customized,ionic,liquid,bis,imide,Li2CO3,ered,LIB,wastes,proposed,novel,Li+,containing,through,filtration,Having,dissociation,ability,extended,structure,generates,sufficiently,osmotic,pressure,drive,efficiently,along,insignificant,reverse,diffusion,produces,against,deionized,surpassing,conventional,NaCl,MgCl2,solutes,higher,recovery,efficiency,smaller,loss,induces,more,stable,permeation,decline,than,which,fluxes,respectively,during,treatment,More,remarkably,unlike,other,require,intensive,energy,input,complicated,processes,recycling,easily,separated,via,solvent,extraction,Reproducible,results,are,achieved,recycled,thus,demon,strates,class,great,potentials,economically
AB值:
0.487989
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