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典型文献
Poly(dimethyl siloxane)anti-corrosion coating with wide pH-responsive and self-healing performance based on core-shell nanofiber containers
文献摘要:
In this research,core-shell electrospun fibers loaded with the shell of cellulose acetate and the core of oleic acid and alkyd varnish resin were synthesized and used within poly(dimethyl siloxane)(PDMS)to prepare self-healing and pH-responsive coatings for a steel substrate.The morphology of the electrospun fibers was characterized by scanning electron microscopy,transmission electron microscopy and confocal fluorescence microscopy.Thermo gravimetric analysis and Fourier transform infrared spectroscopy re-vealed that the self-healing agents were loaded successfully with a loading rate of 2.9%.The properties of the fiber-PDMS composite coating were characterized by water contact angle measurements,mechanical tests,electrochemical impedance spectroscopy,and scanning Kelvin probe.Results show that the max-imum self-healing efficiencies of the fiber-PDMS coating in alkaline and acidic solution are 95.96%and 97.04%,respectively.The composition of the self-healing agents at the damaged part of the coating was verified by an infrared mapping test and using an energy dispersive spectrometer.In addition,the sand-paper abrasion test shows the hydrophobic effect of fiber-PDMS coating remains above 88.2%and de-creases slightly through the addition of abrasion cycles.This research can pave the way for the industrial applications of pH-responsive self-healing coatings.
文献关键词:
作者姓名:
Xiaohong Ji;Wei Wang;Xia Zhao;Lifei Wang;Fubin Ma;Yanli Wang;Jizhou Duan;Baorong Hou
作者机构:
Key Laboratory of Marine Environmental Corrosion and Bio-fouling,Institute of Oceanology,Chinese Academy of Sciences,Qingdao 266071,China;Open Studio for Marine Corrosion and Protection,Pilot National Laboratory for Marine Science and Technology,Qingdao 266237,China;Center for Ocean Mega-Science,Chinese Academy of Science,Qingdao 266071,China;School of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China;School of Materials Science and Engineering,Ocean University of China,238 Songling Road,Qingdao 266100,China
引用格式:
[1]Xiaohong Ji;Wei Wang;Xia Zhao;Lifei Wang;Fubin Ma;Yanli Wang;Jizhou Duan;Baorong Hou-.Poly(dimethyl siloxane)anti-corrosion coating with wide pH-responsive and self-healing performance based on core-shell nanofiber containers)[J].材料科学技术(英文版),2022(06):128-145
A类:
alkyd,varnish
B类:
Poly,dimethyl,siloxane,anti,corrosion,wide,responsive,self,healing,performance,core,shell,nanofiber,containers,In,this,research,electrospun,fibers,loaded,cellulose,acetate,oleic,resin,were,synthesized,used,within,poly,PDMS,prepare,coatings,steel,substrate,morphology,was,characterized,by,scanning,electron,microscopy,transmission,confocal,fluorescence,Thermo,gravimetric,analysis,Fourier,transform,infrared,spectroscopy,vealed,that,agents,successfully,loading,properties,composite,water,contact,angle,measurements,mechanical,tests,electrochemical,impedance,Kelvin,probe,Results,max,imum,efficiencies,alkaline,acidic,solution,respectively,composition,damaged,part,verified,mapping,using,energy,dispersive,spectrometer,addition,sand,paper,abrasion,shows,hydrophobic,effect,remains,above,creases,slightly,through,cycles,This,pave,way,industrial,applications
AB值:
0.55148
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