典型文献
Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production
文献摘要:
Sulfonic acid functionalized mesoporous silica based solid acid catalysts with different morphology were designed and fabricated.The synthesized materials were characterized by various physicochemical and spectro-scopic techniques like scanning electron microscope-energy dispersive X-ray spectroscopy,Fourier transform infrared spectroscopy,Brunauer-Emmett-Teller surface area,thermogravimetric analysis and n-butylamine acidity.The shape of catalysts particles plays an important role in its activity.The sulfonic acid functionalized mesoporous silica catalysts of spherical shape and the cube shape were assessed for catalytic activity in biodiesel production.The catalytic biodiesel production reaction over the catalysts were studied by esterification of free fatty acid,oleic acid with methanol.The effect of various reaction parameters such as catalyst concentration,acid/alcohol molar ratio,catalyst amount,reaction temperature and reaction time on catalytic activity were investigated to optimize the conditions for maximum conversion.It was sulfonated cubic shape mesoporous silica which exhibited better activity as compared to the spherical shape silica catalysts.Additionally,the catalyst was regenerated and reused up to three cycles without any significant loss in activity.The present catalysts exhibit superior performance in biodiesel production and it can be used for the several biodiesel feedstock's that are rich in free fatty acids.
文献关键词:
中图分类号:
作者姓名:
Vinayak Hegde;Parimal Pandit;Pranita Rananaware;Varsha P.Brahmkhatri
作者机构:
Centre for Nano and Material Sciences,Jain University,Jain Global Campus,Bengaluru 562112,India
文献出处:
引用格式:
[1]Vinayak Hegde;Parimal Pandit;Pranita Rananaware;Varsha P.Brahmkhatri-.Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production)[J].化学科学与工程前沿,2022(08):1198-1210
A类:
butylamine
B类:
Sulfonic,functionalized,mesoporous,silica,different,morphology,biodiesel,production,solid,catalysts,were,designed,fabricated,synthesized,materials,characterized,by,various,physicochemical,scopic,techniques,like,scanning,electron,microscope,energy,dispersive,ray,spectroscopy,Fourier,transform,infrared,Brunauer,Emmett,Teller,surface,area,thermogravimetric,analysis,acidity,shape,particles,plays,important,role,its,activity,sulfonic,spherical,cube,assessed,catalytic,reaction,over,studied,esterification,free,fatty,oleic,methanol,effect,parameters,such,concentration,alcohol,molar,amount,temperature,investigated,optimize,conditions,maximum,conversion,It,was,sulfonated,cubic,which,exhibited,better,compared,Additionally,regenerated,reused,three,cycles,without,any,significant,loss,present,superior,performance,several,feedstock,that,rich,acids
AB值:
0.518866
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