典型文献
Photodimerization of azaanthracene derivatives mediated by cucurbit[10]uril
文献摘要：
Challenges of achieving efficient photodimerization of azaanthracene derivatives remain due to the low selectivity and slow reaction rate.In this paper,cucurbit[10]uril(CB[10]),with the largest rigid and hy-drophobic cavity among CB[n]s,was used to affect the photodimerization reaction of four water-soluble 1-(2-)substituted azaanthracene derivatives(1-4).It revealed that 1-4 could form 1:2 host-guest com-plexes with CB[10]in aqueous solution.Irradiation of 1 in the presence of 0.5 equiv.of CB[10]selectively produced a head-to-tail(anti-HT)photodimer product.As for 2-4,CB[10]acted as a nanoreactor accel-erating their photodimerization reaction in water.Our results suggest that photodimerization of azaan-thracene derivatives could be promoted by the CB[10]-based host-guest strategy with high efficiency and selectivity.
文献关键词：
中图分类号：
作者姓名：
Huaxing Li;Xianchen Hu;Fengbo Liu;Dongdong Sun;Yong Wu;Simin Liu
作者机构：
School of Chemistry and Chemical Engineering,Wuhan University of Science and Technology,Wuhan 430081,China;The State Key Laboratory of Refractories and Metallurgy,Institute of Advanced Materials and Nanotechnology,Wuhan University of Science and Technology,Wuhan 430081,China
文献出处：
引用格式：
[1]Huaxing Li;Xianchen Hu;Fengbo Liu;Dongdong Sun;Yong Wu;Simin Liu-.Photodimerization of azaanthracene derivatives mediated by cucurbit[10]uril)[J].中国化学快报（英文版）,2022(12):5124-5127
A类：
Photodimerization,azaanthracene,photodimerization,photodimer,azaan,thracene
B类：
derivatives,mediated,by,cucurbit,uril,Challenges,achieving,efficient,remain,due,selectivity,slow,reaction,In,this,paper,CB,largest,rigid,hy,drophobic,cavity,among,was,used,affect,four,water,soluble,substituted,It,revealed,that,could,form,host,guest,com,plexes,aqueous,solution,Irradiation,presence,equiv,selectively,produced,head,tail,anti,HT,product,acted,nanoreactor,accel,erating,their,Our,results,suggest,be,promoted,strategy,high,efficiency
AB值：
0.539854
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