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典型文献
Kinetic study of CO2 fixation into propylene carbonate with water as efficient medium using microreaction system
文献摘要：
Carbon dioxide(CO2)utilization and fixation have become one of the most important research areas nowadays due to the increase of global greenhouse effect.Cyclic carbonate,which is widely used in var-ious fields,can be synthesized by fixation of CO2 with epoxide in industry.Moreover,the synthesis of cyc-lic carbonate is a 100％atom economical reaction,which makes it eco-friendly and promising.To enhance the reaction efficiency and safety,a microreaction system was used as the platform for cycloaddition reaction.In this work,tetrabutylammonium bromide(TBAB)was chosen as catalyst,and propylene oxide(PO)as a mode substrate.Interestingly,the addition of water can increase the propylene carbonate(PC)yield and decrease the activation energy considerably,proving water as catalyst promoter for PC synthe-sis.PC yield and selectivity could reach 91.6％and 99.8％,respectively.The Influence factors and kinetic equation for CO2 cycloaddition were obtained as well.
文献关键词：
中图分类号：
[1] 医药、卫生（R） / 基础医学（R3） / 病理学（R36） / 病理过程（R364）
[2] 医药、卫生（R） / 药学（R9） / 药理学（R96） / 实验药理学（R965）
[3] 医药、卫生（R） / 神经病学与精神病学（R74） / 神经病学（R741）
作者姓名：
Yuxin Wu;Zhuo Chen;Xiaohui Zhang;Jian Chen;Yundong Wang;Jianhong Xu
作者机构：
The State Key Laboratory of Chemical Engineering,Department of Chemical Engineering,Tsinghua University,Beijing 100084,China
文献出处：
中国化学工程学报（英文版）
引用格式：
[1]Yuxin Wu;Zhuo Chen;Xiaohui Zhang;Jian Chen;Yundong Wang;Jianhong Xu-.Kinetic study of CO2 fixation into propylene carbonate with water as efficient medium using microreaction system)[J].中国化学工程学报（英文版）,2022(10):247-253
A类：
microreaction,tetrabutylammonium
B类：
Kinetic,study,fixation,into,propylene,carbonate,water,efficient,medium,using,system,Carbon,dioxide,utilization,have,become,one,most,important,research,areas,nowadays,due,increase,global,greenhouse,effect,Cyclic,which,widely,used,var,ious,fields,can,synthesized,by,epoxide,industry,Moreover,synthesis,atom,economical,makes,friendly,promising,To,enhance,efficiency,safety,was,platform,cycloaddition,this,work,bromide,TBAB,chosen,catalyst,PO,mode,substrate,Interestingly,yield,decrease,activation,energy,considerably,proving,promoter,selectivity,could,reach,respectively,Influence,factors,kinetic,equation,were,obtained,well
AB值：
0.568999
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