典型文献
Supramolecular interaction controlled and calix[4]arene ligand assisted Pd-catalyzed C(sp3)-H arylation of aliphatic aldehydes
文献摘要：
A calix[4]arene ligand assisted direct β-C-H arylation of tertiary aliphatic aldehydes has been devel-oped via a Pd-catalyzed C(sp3)-H functionalization process.This strategy exhibited good functional group compatibility and C-H bond site-selectivity.Mechanism studies have shown that both synergistic effect and cationic-π supramolecular interaction between calixarene cavity and transition-metal catalytic center may play an important role in this catalytic cycle.This complementary method would be used in organic and medical chemistry due to the importance of tertiary aliphatic aldehydes.
文献关键词：
中图分类号：
作者姓名：
Yao Wu;Zhiyan Ma;Jing Shi;Xiaoqiang Sun;Ke Yang;Zheng-Yi Li
作者机构：
Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology,School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China
文献出处：
引用格式：
[1]Yao Wu;Zhiyan Ma;Jing Shi;Xiaoqiang Sun;Ke Yang;Zheng-Yi Li-.Supramolecular interaction controlled and calix[4]arene ligand assisted Pd-catalyzed C(sp3)-H arylation of aliphatic aldehydes)[J].中国化学快报（英文版）,2022(12):5116-5119
A类：
calixarene
B类：
Supramolecular,interaction,controlled,ligand,assisted,Pd,catalyzed,sp3,arylation,aliphatic,aldehydes,direct,tertiary,has,been,devel,oped,via,functionalization,process,This,strategy,exhibited,good,group,compatibility,bond,site,selectivity,Mechanism,studies,have,shown,that,both,synergistic,effect,cationic,supramolecular,between,cavity,transition,metal,catalytic,center,may,play,important,role,this,cycle,complementary,method,would,used,organic,medical,chemistry,due,importance
AB值：
0.639151
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