典型文献
Anchoring metal ions in amine-functionalized boron imidazolate framework for photocatalytic reduction of CO2
文献摘要：
The photocatalytic reduction of CO2 to energy-rich chemicals is highly appealing for alleviation of energy crisis and environment pollution.The introduction of different active sites is a key factor to determine the reaction activity and selectivity.Here,we demonstrate the metal ion-dependent performance for pho-tocatalytic CO2 reduction by anchoring transition metal ions(Co2+and Ni2+)in an amine-functionalized boron imidazolate framework(BIF-43).As a result,Ni@BIF-43 realized a high selectivity of 90.2％for the CO2-to-CO,while Co@BIF-43 achieved more efficient conversion with a high CO production rate of 2036.0 pmol g-1 h-1.Significantly,precise control of isolated metal site on a well-defined structure through coordination-assisted strategies enables us to better understand the specific effects of different metal-ion species on photoreduction of CO2 as well as the catalytic mechanism.
文献关键词：
中图分类号：
作者姓名：
Guilan Xu;Qin-Long Hong;Yayong Sun;Meng Liu;Hai-Xia Zhang;Jian Zhang
作者机构：
State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China;Key Lab for Sport Shoes Upper Materials of Fujian Province,Fujian Huafeng New Material Co.,Ltd.,Putian 351164,China
文献出处：
引用格式：
[1]Guilan Xu;Qin-Long Hong;Yayong Sun;Meng Liu;Hai-Xia Zhang;Jian Zhang-.Anchoring metal ions in amine-functionalized boron imidazolate framework for photocatalytic reduction of CO2)[J].中国化学快报（英文版）,2022(06):2915-2918
A类：
B类：
Anchoring,metal,ions,amine,functionalized,boron,imidazolate,framework,photocatalytic,energy,rich,chemicals,highly,appealing,alleviation,crisis,environment,pollution,introduction,different,active,sites,key,determine,reaction,activity,selectivity,Here,demonstrate,dependent,performance,by,anchoring,transition,Co2+and,Ni2+,BIF,result,realized,while,achieved,more,efficient,conversion,production,pmol,Significantly,precise,control,isolated,well,defined,structure,through,coordination,assisted,strategies,enables,us,better,understand,specific,effects,species,photoreduction,mechanism
AB值：
0.555635
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