典型文献
Electrocatalytic construction of the C-N bond from the derivates of CO2 and N2
文献摘要：
Electrochemical synthesis of C-N bond-containing com-pounds(e.g.,urea,amino acid,amide,amine,and their de-rivates)from CO2/N2 and their derivates is emerging as a promising sustainable strategy[1-7].CO2 and its derived products,CO,HCOOH,(COOH)2,etc.,could serve as car-bon sources(Figure 1)[8].N2,making up 80％of air,is an appealing nitrogen source.However,the low solubility of N2 and the high dissociation energy for the N≡N bond limit its application.The recent advances in renewable energy-driven nitrogen fixation techniques are expected to provide green active nitrogen sources.Specifically,photocatalytic or elec-trocatalytic oxidation of N2 to NOx/NO3-has been achieved recently by our group[9-12].Now,the development of clean electricity has reawakened the interest in plasma-/electro-catalytic nitrogen fixation.Combining the renewable-en-ergy-driven C/N precursor activation/conversion with the subsequent electrocatalytic C-N coupling is an alternative way to realize high selectivity synthesis of the target pro-ducts.The bottleneck for this technique lies in the compe-titive relationship between the C-N coupling reaction and the sole reduction of the C/N precursor.To obtain a high current density,a big applied potential is usually required,accompanied by the occurrence of side reactions,resulting in the decrease of Faradaic efficiency.
文献关键词：
中图分类号：
作者姓名：
Yanmei Huang;Yuting Wang;Yongmeng Wu;Yifu Yu;Bin Zhang
作者机构：
Institute of Molecular Plus,Department of Chemistry,School of Science,Tianjin University,Tianjin 300072,China
文献出处：
引用格式：
[1]Yanmei Huang;Yuting Wang;Yongmeng Wu;Yifu Yu;Bin Zhang-.Electrocatalytic construction of the C-N bond from the derivates of CO2 and N2)[J].中国科学:化学（英文版）,2022(02):204-206
A类：
rivates,reawakened,titive
B类：
Electrocatalytic,construction,bond,from,derivates,N2,Electrochemical,synthesis,containing,pounds,urea,amino,acid,amide,amine,their,emerging,promising,sustainable,strategy,its,derived,products,HCOOH,etc,could,serve,car,sources,Figure,making,air,appealing,nitrogen,However,low,solubility,high,dissociation,energy,limit,application,advances,renewable,driven,fixation,techniques,are,expected,provide,green,active,Specifically,photocatalytic,oxidation,NOx,NO3,has,been,achieved,recently,by,group,Now,development,clean,electricity,interest,plasma,Combining,precursor,activation,conversion,subsequent,electrocatalytic,coupling,alternative,way,realize,selectivity,target,bottleneck,this,lies,compe,relationship,between,sole,reduction,To,obtain,current,density,big,applied,potential,usually,required,accompanied,occurrence,side,reactions,resulting,decrease,Faradaic,efficiency
AB值：
0.584342
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