典型文献
Facile synthesis of(β-chlorodifluoroethyl)phosphonates via chlorination reaction of difluoroalkyl diazo derivatives with HCl
文献摘要：
An efficient chlorination reaction of in situ generated(β-diazo-α,α-difluoroethyl)phosphonates has been achieved with hydrochloric acid as a chlorine source under mild and operationally convenient conditions.The reaction does not need any catalyst and tolerates a wide scope of substrates,which affords the(β-chlorodifluoroethyl)phosphonate products in good to excellent yields.This reaction represents the first example of the halogenation of difluoroalkyl diazo compounds,and also provides an easy way for the synthesis of difluoromethylenephosphonate-containing compounds.
文献关键词：
中图分类号：
作者姓名：
Jiang Liu;Romana Pajkert;Li Wang;Haibo Mei;Gerd-Volker R?schenthaler;Jianlin Han
作者机构：
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources,International Innovation Center for Forest Chemicals and Materials,College of Chemical Engineering,Nanjing Forestry University,Nanjing 210037,China;Department of Life Sciences and Chemistry,Jacobs University Bremen gGmbH,Campus Ring 1,Bremen 28759,Germany
文献出处：
引用格式：
[1]Jiang Liu;Romana Pajkert;Li Wang;Haibo Mei;Gerd-Volker R?schenthaler;Jianlin Han-.Facile synthesis of(β-chlorodifluoroethyl)phosphonates via chlorination reaction of difluoroalkyl diazo derivatives with HCl)[J].中国化学快报（英文版）,2022(05):2429-2432
A类：
chlorodifluoroethyl,phosphonates,difluoroalkyl,difluoroethyl,difluoromethylenephosphonate
B类：
Facile,synthesis,via,chlorination,reaction,diazo,derivatives,HCl,An,efficient,situ,generated,has,been,achieved,hydrochloric,acid,chlorine,source,under,mild,operationally,convenient,conditions,does,not,need,any,catalyst,tolerates,wide,scope,substrates,which,affords,products,good,excellent,yields,This,represents,first,example,halogenation,compounds,also,provides,easy,way,containing
AB值：
0.577522
相似文献
机标中图分类号，由域田数据科技根据网络公开资料自动分析生成，仅供学习研究参考。
