典型文献
Four-step spin-crossover in an oxamide-decorated metal-organic framework
文献摘要：
Spin-crossover(SCO)complexes with multiple spin states are promising candidates for high-order magnetic storage and multiple switches.Here,by employing the N,N'-4-dipyridyloxalamide(dpo)lig-and,we synthesize two Hofmann-type metal-organic frameworks(MOFs)[Fe(dpo){Ag(CN)2}2]·3DMF(1)and[Fe(dpo){Ag(CN)2}2]·0.5MeCN,2DEF(2).which exhibit guest dependent four-step SCO be-haviors with the sequences of LS →～LS2/3HS1/3 → LS1/2HS1/2 →～LS3/10HS7/10 → HS and LS →～LS2/3HS1//3 → LS11/2HS1/2 →～LS1/4HS3/4 → HS,respectively.Therefore,the incorporation of hydrogen-donating/hydrogen-accepting groups into the Hofmann-type MOFs may effectively explore the multi-step SCO materials by tuning hydrogen-bonding interactions.
文献关键词：
中图分类号：
作者姓名：
Siguo Wu;Sukhen Bala;Zeyu Ruan;Guozhang Huang;Zhaoping Ni;Mingliang Tong
作者机构：
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education,School of Chemistry,Sun Yat-Sen University,Guangzhou 510275,China
文献出处：
引用格式：
[1]Siguo Wu;Sukhen Bala;Zeyu Ruan;Guozhang Huang;Zhaoping Ni;Mingliang Tong-.Four-step spin-crossover in an oxamide-decorated metal-organic framework)[J].中国化学快报（英文版）,2022(03):1381-1384
A类：
oxamide,dipyridyloxalamide,dpo,3DMF,5MeCN,2DEF,3HS1,2HS1,10HS7,LS11,4HS3
B类：
Four,step,spin,crossover,decorated,metal,organic,Spin,SCO,complexes,multiple,states,are,promising,candidates,high,order,magnetic,storage,switches,Here,by,employing,lig,we,synthesize,two,Hofmann,type,frameworks,MOFs,Ag,which,exhibit,guest,dependent,four,be,haviors,sequences,LS2,LS3,respectively,Therefore,incorporation,hydrogen,donating,accepting,groups,into,may,effectively,explore,materials,tuning,bonding,interactions
AB值：
0.473775
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