Highly selective separation of propylene/propane mixture on cost-effectively four-carbon linkers based metal-organic frameworks|Daofei Lv;Junhao Xu;Pingjun Zhou;Shi Tu;Feng Xu;Jian Yan;Hongxia Xi;Zewei Liu;Wenbing Yuan;Qiang Fu;Xin Chen;Qibin Xia|School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510641,China - 期刊导航|首站-论文投稿智能助手|论文发表|论文智能投稿|期刊自助发表推荐|杂志社快速发表|查同导刊-域田数据官方网站

典型文献

Highly selective separation of propylene/propane mixture on cost-effectively four-carbon linkers based metal-organic frameworks

文献摘要：

The separation of propylene and propane is an important but challenging process,primarily achieved through energy-intensive distillation technology in the petrochemical industry.Here,we reported two natural C4 linkers based metal-organic frameworks(MIP-202 and MIP-203)for C3H6/C3H8 separation.Adsorption isotherms and selectivity calculations were performed to study the adsorption performance for C3H6/C3H8 separation.Results show that C3H6/C3H8 uptake ratios(298 K,100 kPa)for MIP-202 and MIP-203 are 2.34 and 7.4,respectively.C3H6/C3H8 uptake ratio(303 K,100 kPa)for MIP-203 is up to 50.0.The mechanism for enhanced separation performance of C3H6/C3H8 on MIP-203 at higher temper-ature(303 K)was revealed by the in situ PXRD characterization.The adsorption selectivities of C3H6/C3H8 on MIP-202 and MIP-203(298 K,100 kPa)are 8.8 and 551.4,respectively.The mechanism for the pref-erential adsorption of C3H6 over C3H8 in MIP-202 and MIP-203 was revealed by the Monte Carlo simula-tion.The cost of organic ligands for MIP-202 and MIP-203 was lower than that of organic ligands for those top-performance MOFs.Our work sets a new benchmark for C3H6 sorbents with high adsorption selectivities.

文献关键词：

中图分类号：

[1] 医药、卫生（R） / 药学（R9） / 药理学（R96） / 实验药理学（R965）

[2] 自动化技术、计算机技术（TP） / 计算技术、计算机技术（TP3） / 计算机的应用（TP39） / 信息处理(信息加工)（TP391）

[3] 数理科学和化学（O） / 力学（O3） / 振动理论（O32） / 非线性振动（O322）

作者姓名：

Daofei Lv;Junhao Xu;Pingjun Zhou;Shi Tu;Feng Xu;Jian Yan;Hongxia Xi;Zewei Liu;Wenbing Yuan;Qiang Fu;Xin Chen;Qibin Xia

作者机构：

School of Environmental and Chemical Engineering,Foshan University,Foshan 528000,China;School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510641,China;Sichuan Jinyuansheng New Energy Technology Co.,Ltd,Meishan 620010,China

文献出处：

中国化学工程学报（英文版）

引用格式：

[1]Daofei Lv;Junhao Xu;Pingjun Zhou;Shi Tu;Feng Xu;Jian Yan;Hongxia Xi;Zewei Liu;Wenbing Yuan;Qiang Fu;Xin Chen;Qibin Xia-.Highly selective separation of propylene/propane mixture on cost-effectively four-carbon linkers based metal-organic frameworks)[J].中国化学工程学报（英文版）,2022(11):126-134

A类：

erential

B类：

Highly,selective,separation,propylene,propane,mixture,cost,effectively,four,carbon,linkers,metal,organic,frameworks,important,but,challenging,process,primarily,achieved,through,energy,intensive,distillation,technology,petrochemical,industry,Here,reported,two,natural,C4,MIP,C3H6,C3H8,Adsorption,isotherms,selectivity,calculations,were,performed,study,adsorption,performance,Results,show,that,uptake,ratios,kPa,are,respectively,mechanism,enhanced,higher,temper,ature,was,revealed,by,situ,PXRD,characterization,selectivities,pref,over,Monte,Carlo,simula,ligands,lower,than,those,top,MOFs,Our,sets,new,benchmark,sorbents

AB值：

0.470756

相似文献

Enhanced photocatalytic performance of S-doped covalent triazine framework for organic pollutant degradation

Yi SHEN;Jing-yu HU;Lun LU;Chao ZHU;Qi-le FANG;Shuang SONG-College of Environment,Zhejiang University of Technology,Hangzhou 310032,China;State Environmental Protection Key Laboratory of Environmental Pollution Health Risk Assessment,South China Institute of Environmental Sciences,Ministry of Ecology and Environment,Guangzhou 510655,China;College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310032,China;Advanced Institute of Natural Sciences,Beijing Normal University at Zhuhai,Zhuhai 519087,China

Hydration reactivity difference between dicalcium silicate and tricalcium silic-ate revealed from structural and Bader charge analysis

Chongchong Qi;Xinhang Xu;Qiusong Chen-School of Resources and Safety Engineering,Central South University,Changsha 410083,China;School of Molecular Science,University of Western Australia,Perth 6009,Australia

Efficient separation between trivalent americium and lanthanides enabled by a phenanthroline-based polymeric organic framework

Afshin Khayambashi;Long Chen;Xue Dong;Kai Li;Zhipeng Wang;Linwei He;Suresh Annam;Lixi Chen;Yaxing Wang;Matthew V.Sheridan;Chao Xu;Shuao Wang-State Key Laboratory of Radiation Medicine and Protection,School for Radiological and Interdisciplinary Sciences(RAD-X)and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions,Soochow University,Suzhou 215123,China;Institute of Nuclear and New Energy Technology,Tsinghua University,Beijing 100084,China

Nitrogen-rich carbon nitrogen polymers for enhancing the sorption of uranyl

Zeru Wang;Wenhao Li;Linzhen Wu;Zhuang Wang;Yalan Cao;Jingkai Cheng;Guangyuan Chen;Qian Zhao;Mei Jiang;Zhengguo Chen;Lin Zhu;Tao Duan-National Co-Innovation Center for Nuclear Waste Disposal and Environmental Safety,Southwest University of Science and Technology,Mianyang 621010,China;State Key Laboratory of Environment-friendly Energy Materials,School of National Defence Science and Technology,Southwest University of Science and Technology,Mianyang 621010,China;College of Chemistry,Sichuan University,Chengdu 610064,China;School of Physics and Astronomy,China West Normal University,Nanchong 637002,China;NHC Key Laboratory of Nuclear Technology Medical Transformation,Mianyang Central Hospital,Mianyang 621010,China

Experimental and theoretical insights into copper phthalocyanine-based covalent organic frameworks for highly efficient radioactive iodine capture