典型文献
Supported Pt-Ni bimetallic nanoparticles catalyzed hydrodeoxygenation of dibenzofuran with high selectivity to bicyclohexane
文献摘要:
Catalytic hydrodeoxygenation (HDO) is one of the most effective methods to upgrade the oxygen-containing compounds derived from coal tar to valuable hydrocarbons.Herein,an efficient bimetallic catalyst Pt1Ni4/MgO was prepared and applied in the HDO of dibenzofuran (DBF).High yield (95%) of the desired product bicyclohexane (BCH) was achieved at 240 ℃ and 1.2 MPa of H2.Superior catalytic performance could be ascribed to the "relay catalysis" of Pt sites and Ni sites,and the reaction pathway is proposed as well.Scale-up experiment and recyclability test were also performed,which demonstrated the recyclability and promising potential application of Pt1 Ni4/MgO.
文献关键词:
中图分类号:
作者姓名:
Pengyu Wu;Chun Cai
作者机构:
Chemical Engineering College,Nanjing University of Science and Technology,Nanjing 210094,China
文献出处:
引用格式:
[1]Pengyu Wu;Chun Cai-.Supported Pt-Ni bimetallic nanoparticles catalyzed hydrodeoxygenation of dibenzofuran with high selectivity to bicyclohexane)[J].中国化学快报(英文版),2022(01):234-238
A类:
dibenzofuran,bicyclohexane,Pt1Ni4
B类:
Supported,bimetallic,nanoparticles,catalyzed,hydrodeoxygenation,high,selectivity,Catalytic,HDO,one,most,effective,methods,upgrade,containing,compounds,derived,from,coal,tar,valuable,hydrocarbons,Herein,efficient,catalyst,MgO,was,prepared,applied,DBF,High,yield,desired,product,BCH,achieved,H2,Superior,catalytic,performance,could,ascribed,relay,catalysis,sites,reaction,pathway,proposed,well,Scale,experiment,recyclability,test,were,also,performed,which,demonstrated,promising,potential,application
AB值:
0.594915
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