Measurements of column-averaged dry-air mole fractions of carbon dioxide and carbon monoxide,CO2(XCO2)and CO(XCO),were performed throughout 2019 at an urban site in Beijing using a compact Fourier Transform Spectrometer(FTS)EM27/SUN.This data set is used to assess the characteristics of combustion-related CO2 emissions of urban Beijing by analyzing the correlated daily anomalies of XCO and XCO2(e.g.,△XCO and △XCO2).The EM27/SUN measurements were calibrated to a 125HR-FTS at the Xianghe station by an extra EM27/SUN instrument transferred between two sites.The ratio of △XCO over △XCO2(△XCO:△XCO2)is used to estimate the combustion efficiency in the Beijing region.A high correlation coefficient(0.86)between △XCO and △XCO2 is observed.The CO:CO2 emission ratio estimated from inventories is higher than the observed △XCO:△XCO2(10.46±0.11 ppb ppm-1)by 42.54％-101.15％,indicating an underestimation in combustion efficiency in the inventories.Daily △XCO:△XCO2 are influenced by transportation governed by weather conditions,except for days in summer when the correlation is low due to the terrestrial biotic activity.By convolving the column footprint[ppm(umol m-2 s-1)-1]generated by the Weather Research and Forecasting-X-Stochastic Time-Inverted Lagrangian Transport models(WRF-X-STILT)with two fossil-fuel emission inventories(the Multi-resolution Emission Inventory for China(MEIC)and the Peking University(PKU)inventory),the observed enhancements of CO2 and CO were used to evaluate the regional emissions.The CO2 emissions appear to be underestimated by 11％and 49％for the MEIC and PKU inventories,respectively,while CO emissions were overestimated by MEIC(30％)and PKU(35％)in the Beijing area.

Ke CHE;Yi LIU;Zhaonan CAI;Dongxu YANG;Haibo WANG;Denghui JI;Yang YANG;Pucai WANG

Key Laboratory of Middle Atmosphere and Global Environment Observation,Institute of Atmospheric Physics,Chinese Academy of Science,Beijing 100029,China;Carbon Neutrality Research Center,Institute of Atmospheric Physics,Chinese Academy of Science,Beijing 100029,China;University of Chinese Academy of Science,Beijing 100049,China

大气科学进展（英文版）

[1]Ke CHE;Yi LIU;Zhaonan CAI;Dongxu YANG;Haibo WANG;Denghui JI;Yang YANG;Pucai WANG-.Characterization of Regional Combustion Efficiency using △XCO∶△XCO2 Observed by a Portable Fourier-Transform Spectrometer at an Urban Site in Beijing)[J].大气科学进展（英文版）,2022(08):1299-1315

XCO,EM27,125HR,Xianghe,convolving,STILT

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