典型文献
Effects of Zr content on electrochemical performance of Ti/Sn–Ru–Co–ZrOx electrodes
文献摘要:
The low cell voltage during electrolytic Mn from the MnCl2 system can effectively reduce the power consumption. In this work, the Ti/Sn?Ru?Co?Zr modified anodes were obtained by using thermal decomposition oxidation. The physical parameters of coatings were ob-served by SEM (scanning electron microscope). Based on the electrochemical performance and SEM/XRD (X-ray diffraction) of the coatings, the influence of Zr on electrode performance was studied and analyzed. When the mole ratio of Sn?Ru?Co?Zr is 6:1:0.8:0.3, the cracks on the surface of coatings were the smallest, and the compactness was the best due to the excellent filling effect of ZrO2 nanoparticles. Moreover, the electrode prepared under this condition had the lowest mass transfer resistance and high chloride evolution activity in the 1mol% NH4Cl and 1.5mol% HCl system. The service life of 3102 h was achieved according to the empirical formula of accelerated-life-test of the new type anode.
文献关键词:
中图分类号:
作者姓名:
Linhui Chang;Sheng Chen;Xionghui Xie;Buming Chen;Haihong Qiao;Hui Huang;Zhongcheng Guo;Ruidong Xu
作者机构:
Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Kunming 650093,China;Research Center of Metallurgical Electrode Materials Engineering Technology,Kunming 650106,China;Kunming Hendera Science and Technology Co.,Ltd.,Kunming 650106,China;North Night Vision Technology Research Institute Group Co.,Ltd.Optical Company,Kunming 650093,China
文献出处:
引用格式:
[1]Linhui Chang;Sheng Chen;Xionghui Xie;Buming Chen;Haihong Qiao;Hui Huang;Zhongcheng Guo;Ruidong Xu-.Effects of Zr content on electrochemical performance of Ti/Sn–Ru–Co–ZrOx electrodes)[J].矿物冶金与材料学报,2022(12):2181-2188
A类:
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Effects,content,electrochemical,performance,Ti,Sn,Ru,Co,ZrOx,electrodes,voltage,during,electrolytic,from,MnCl2,system,effectively,reduce,power,consumption,In,this,work,modified,anodes,were,obtained,by,using,thermal,decomposition,oxidation,physical,parameters,coatings,served,scanning,electron,microscope,Based,ray,diffraction,influence,was,studied,analyzed,When,mole,ratio,cracks,surface,smallest,compactness,best,due,excellent,filling,ZrO2,nanoparticles,Moreover,prepared,under,condition,had,lowest,mass,transfer,resistance,high,chloride,evolution,activity,1mol,NH4Cl,5mol,HCl,service,life,achieved,according,empirical,formula,accelerated,test,new,type
AB值:
0.62021
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